The Effect of Alkyl Substituents on the Formation and Structure of Homochiral (<i>R</i>*,<i>R</i>*)-[R<sub>2</sub>Ga(<i>µ</i>-OCH(Me)CO<sub>2</sub>R′)]<sub>2</sub> Species—Towards the Factors Controlling the Stereoselectivity of Dialkylgallium Alkoxides in the Ring-Opening Polymerization of <i>rac</i>-Lactide

The Effect of Alkyl Substituents on the Formation and Structure of Homochiral (<i>R</i>*,<i>R</i>*)-[R<sub>2</sub>Ga(<i>µ</i>-OCH(Me)CO<sub>2</sub>R′)]<sub>2</sub> Species—Towards the Factors Controlling the Stereoselectivity of Dialkylgallium Alkoxides in the Ring-Opening Polymerization of <i>rac</i>-Lactide

Building on our previous studies, which have demonstrated that homochiral propagating species—(<i>R</i>*,<i>R</i>*)-[Me<sub>2</sub>Ga(<i>µ</i>-OCH(Me)CO<sub>2</sub>R)]<sub>2</sub>—were crucial for the heteroselectivity of [Me<...

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Bibliographic Details
Main Authors: Magdalena Kaźmierczak, Łukasz Dobrzycki, Maciej Dranka, Paweł Horeglad
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Molecules
Subjects:
biodegradable polyesters
polylactide
tacticity
heterotactic
dimers
diastereomers
Online Access:https://www.mdpi.com/1420-3049/30/1/190
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