Green Synthesis of Trifluoromethanesulfonyl Fluoride as an Eco-Friendly Alternative to SF<sub>6</sub> Gas Insulation and Analysis of Its Acute Inhalation Toxicity

Green Synthesis of Trifluoromethanesulfonyl Fluoride as an Eco-Friendly Alternative to SF<sub>6</sub> Gas Insulation and Analysis of Its Acute Inhalation Toxicity

This study demonstrates an eco-friendly synthesis of trifluoromethanesulfonyl fluoride (TFSF) as a sustainable SF<sub>6</sub> alternative. Optimized halogen exchange reactions using CF<sub>3</sub>SO<sub>2</sub>Cl/KF (3:1 ratio) with crown ether catalysis at low te...

Full description

Saved in:

Bibliographic Details
Main Authors:	Shile Wang, Li Dong, Ruichao Peng, Hongding Tang
Format:	Article
Language:	English
Published:	MDPI AG 2025-05-01
Series:	Molecules
Subjects:	TFSF green synthesis halogen exchange acute inhalation toxicity SF<sub>6</sub> alternative
Online Access:	https://www.mdpi.com/1420-3049/30/10/2241
Tags:	Add Tag No Tags, Be the first to tag this record!

Similar Items

An Investigation of WO<sub>3</sub>/V<sub>2</sub>O<sub>5</sub>/TiO<sub>2</sub> Catalysts: Effects of WO<sub>3</sub> on Morphology, Thermal Stability, and Activity for the Catalytic Oxidation of Dimethyl Sulfide
by: Gaytri Sharma, et al.
Published: (2025-06-01)

RESEARCH OF THE INFLUENCE OF IMPURITIES DYSPROSIUM AND THULIUM ON THE LUMINESCENCE OF SOLID SOLUTIONS Y<sub>1– <i>x</i></sub>Yb <i><sub>x</sub> </i>Al<sub>3</sub>(BO<sub>3</sub>)<sub>4</sub>
by: Sergey Vladimirovich Kostyukov
Published: (2022-05-01)

Unlocking Synergistic Photo-Fenton Catalysis with Magnetic SrFe<sub>12</sub>O<sub>19</sub>/g-C<sub>3</sub>N<sub>4</sub> Heterojunction for Sustainable Oxytetracycline Degradation: Mechanisms and Applications
by: Song Cui, et al.
Published: (2025-05-01)

Structural, Optical, Magnetic, and Dielectric Investigations of Pure and Co-Doped La<sub>0.67</sub>Sr<sub>0.33</sub>Mn<sub>1-x-y</sub>Zn<sub>x</sub>Co<sub>y</sub>O<sub>3</sub> Manganites with (0.00 < x + y < 0.20)
by: Mansour Mohamed, et al.
Published: (2024-11-01)

Synthesis, Structure and Magnetic Properties of Sm<sub>6−<i>x</i></sub>La<i><sub>x</sub></i>Mn<sub>23</sub> (0.5 ≤ <i>x</i> ≤ 4) Alloys
by: Ying-Hua Liang, et al.
Published: (2025-05-01)

N<sub>3C</sub>-Defect-Tuned g-C<sub>3</sub>N<sub>4</sub> Photocatalysts: Structural Optimization and Enhanced Tetracycline Degradation Performance
by: Yu Lu, et al.
Published: (2025-03-01)

Novel Visible Light-Driven Ho<sub>2</sub>InSbO<sub>7</sub>/Ag<sub>3</sub>PO<sub>4</sub> Photocatalyst for Efficient Oxytetracycline Contaminant Degradation
by: Jingfei Luan, et al.
Published: (2025-08-01)

Facile Synthesis and Characterization of Novel Fe<sub>0.65</sub>Mg<sub>0.35</sub>Cr<sub>2</sub>O<sub>4</sub>@C Nanocomposite for Efficient Removal of Cd(II) Ions from Aqueous Media
by: Ehab A. Abdelrahman, et al.
Published: (2025-03-01)

Microstructure and Electrochemical Properties of Pure and Vanadium-Doped Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub> Nanoflakes for High Performance Supercapacitors
by: Mudda Deepak, et al.
Published: (2025-07-01)

Preparation of CdIn<sub>2</sub>S<sub>4</sub>/TiO<sub>2</sub> Nanocomposites and Its Photocathodic Protection Properties for Q235 Carbon Steel
by: SONG Wei - zhe, LI Hong, CUI Xing - qiang, LI Yan - hui, CHENG Lian - jun, LI Jun - ru
Published: (2021-03-01)

Effect of CaO Content on the Photoluminescence Excitation and Emission Properties of Bi<sub>2</sub>O<sub>3</sub> and ZnO-Co-Doped Ca<sub>2+<i>x</i></sub>Ga<sub>4</sub>O<sub>8+<i>x</i></sub> Phosphors
by: Shu-Han Liao, et al.
Published: (2025-06-01)

Investigations of single crystals of the ternary compound CuIn<sub>7</sub>S<sub>11</sub>
by: V. V. Shatalova
Published: (2019-06-01)

SPECT and MRI Evaluation of Cerebrovascular Reactivity with CO<sub>2</sub> Inhalation—A Preliminary Study
by: Min-Gyu Song, et al.
Published: (2025-05-01)

Unlocking the Potential of Na<sub>2</sub>Ti<sub>3</sub>O<sub>7</sub>-C Hollow Microspheres in Sodium-Ion Batteries via Template-Free Synthesis
by: Yong-Gang Sun, et al.
Published: (2025-03-01)

Influence of Y<sub>2</sub>O<sub>3</sub> Concentration on the Optical Properties of Multicomponent Glasses and Glass–Ceramics
by: Akram Beniaiche, et al.
Published: (2024-11-01)

Study on the High-Temperature Corrosion Behavior of Cr<sub>3</sub>C<sub>2</sub>/Cr<sub>2</sub>AlC MAX Phase Composite Coatings on Stainless Steel Surfaces in Molten Sodium Polysulfide
by: CUI Xingcheng, REN Yanjie, XIAO Biao, LI Yanhua, CHEN Jian, ZHOU Libo, QIU Wei, HUANG Weiying, NIU Yan
Published: (2025-06-01)

Distinctive Effects of Fullerene C<sub>60</sub> and Fullerenol C<sub>60</sub>(OH)<sub>24</sub> Nanoparticles on Histological, Molecular and Behavioral Hallmarks of Alzheimer’s Disease in APPswe/PS1E9 Mice
by: Sholpan Askarova, et al.
Published: (2025-07-01)

Enhanced UVC Responsivity of Heteroepitaxial α-Ga<sub>2</sub>O<sub>3</sub> Photodetector with Ultra-Thin HfO<sub>2</sub> Interlayer
by: SiSung Yoon, et al.
Published: (2025-07-01)

Effects of Different Y<sub>2</sub>O<sub>3</sub> Contents on the Microstructure of Ni-Based WC Ceramic Composite Coating by Laser Cladding
by: JIN Lijun, LIU Zhenzhen
Published: (2025-05-01)

Evolution of CHA<sub>2</sub>DS<sub>2</sub>-VASc Score for Predicting Risk of Stroke Development in Patients with Atrial Fibrillation
by: A. O. Rubanenko
Published: (2023-05-01)

High Dielectric Tunability and Figure of Merit at Low Voltage in (001)-Oriented Epitaxial Tetragonal Pb<sub>0.52</sub>Zr<sub>0.48</sub>TiO<sub>3</sub> Thin Films
by: Hongwang Li, et al.
Published: (2025-05-01)

Study on Synergistic Effect of La<sub>2</sub>O<sub>3</sub> Nanoparticles and Silane in Copper Alloy Surface Treatment Solution
by: LV Xue-fei, LV Ying, LU Hong-jie, GAN Shu-kun, SHI Long
Published: (2021-02-01)

Fe<sub>3</sub>O<sub>4</sub>@β-cyclodextrin Nanosystem: A Promising Adjuvant Approach in Cancer Treatment
by: Claudia Geanina Watz, et al.
Published: (2025-08-01)

Non-empirical calculations of minimal energetic ways of addition of H<sub>2</sub>F<sub>2</sub> and H<sub>2</sub>Cl<sub>2</sub> molecules to acetylene and methylacetylene molecules
by: Yu. B. Kirillov, et al.
Published: (2012-12-01)

Mg<sup>2+</sup> and Cr<sup>3+</sup> Co-Doped LiNi<sub>0.5</sub>Mn<sub>1.5</sub>O<sub>4</sub> Derived from Ni/Mn Bimetal Oxide as High-Performance Cathode for Lithium-Ion Batteries
by: Dehua Ma, et al.
Published: (2025-03-01)

Construction of Chitin-Based Composite Hydrogel via AlCl<sub>3</sub>/ZnCl<sub>2</sub>/H<sub>2</sub>O Ternary Molten Salt System and Its Flexible Sensing Performance
by: Yanjun Lv, et al.
Published: (2025-06-01)

Nano-Biochar Enhanced Adsorption of NO<sub>3</sub><sup>−</sup>-N and Its Role in Mitigating N<sub>2</sub>O Emissions: Performance and Mechanisms
by: Weimin Xing, et al.
Published: (2025-07-01)

S-Doped FeOOH Layers as Efficient Hole Transport Channels for the Enhanced Photoelectrochemical Performance of Fe<sub>2</sub>O<sub>3</sub>
by: Yanhong Zhou, et al.
Published: (2025-05-01)

Understanding the Interface Characteristics Between TiB<sub>2</sub>(0001) and L1<sub>2</sub>-Al<sub>3</sub>Zr(001): A First-Principles Investigation
by: Xingzhi Pang, et al.
Published: (2024-11-01)

Band-Engineered α-Fe<sub>2</sub>O<sub>3</sub>@NiO P-N Heterojunction for Room-Temperature NH<sub>3</sub> Detection and Real-Time Meat Spoilage Monitoring
by: Mingjia Li, et al.
Published: (2025-06-01)

Transformation of alkanes under treatment of single impulse of hydrodynamic cavitation. II. Behaviour of medium-chain alkanes С<sub>21</sub>–С<sub>38</sub>
by: V. N. Torhovsky, et al.
Published: (2014-08-01)

Effect of CTAB on the Morphology of Sn-MOF and the Gas Sensing Performance of SnO<sub>2</sub> with Different Crystal Phases for H<sub>2</sub> Detection
by: Manyi Liu, et al.
Published: (2025-05-01)

STUDY OF ELECTROLUMINESCENCE OF STRUCTURE BASED ON ZnS:Cu,Cl WITH PHOTOCONVERTER Y<sub>3</sub>Al<sub>5</sub>O<sub>12</sub>:Ce
by: Leonid Vasilievich Mikhnev, et al.
Published: (2022-05-01)

Tailored Magnetic Fe<sub>3</sub>O<sub>4</sub>-Based Core–Shell Nanoparticles Coated with TiO<sub>2</sub> and SiO<sub>2</sub> via Co-Precipitation: Structure–Property Correlation for Medical Imaging Applications
by: Elena Emanuela Herbei, et al.
Published: (2025-07-01)

Nitrogen-Doped Carbon Dots as a Fluorescent “Off–On” Probe for Selective Ascorbic Acid Detection via H<sub>2</sub>O<sub>2</sub>-Mediated Quenching
by: Jingjing Jia, et al.
Published: (2025-06-01)

Highly Transparent Yb:Y<sub>2</sub>O<sub>3</sub> Laser Ceramics with High Thermal Conductivity Obtained via a Sintering-Additive-Free Strategy
by: Zhongchao Fu, et al.
Published: (2025-06-01)

Structure and Properties of Micro-Arc Oxidation Coating on Aluminium Alloy via α-Al<sub>2</sub>O<sub>3</sub> and Graphene Oxide Doping
by: YUAN Shaohua, FENG Jun, QI Huarong, DENG Shengyong, CHENG Junjie
Published: (2025-07-01)

Conversion of alkanes under single pulse of hydrodynamic cavitation. I. Behavior of C<sub>13</sub>–C<sub>15</sub> alkanes
by: V. N. Torhovsky, et al.
Published: (2013-12-01)

Cu-Doping Induced Structural Transformation and Magnetocaloric Enhancement in CoCr<sub>2</sub>O<sub>4</sub> Nanoparticles
by: Ming-Kang Ho, et al.
Published: (2025-07-01)

Electrostatic Field Modification Enhances the Electrocatalytic Oxygen Evolution Reaction Stability of CoFe<sub>2</sub>O<sub>4</sub> Catalysts
by: Liwen Liang, et al.
Published: (2025-04-01)