The Sorption of Th(IV) Ions onto Montmorillonite: The Effect of pH, Ionic Strength and Fulvic Acid

Thorium was considered as a chemical analogue of other tetravalent actinides. The sorption of Th(IV) ions onto montmorillonite and its cross-linked counterpart in the presence/absence of fulvic acid was investigated via a batch technique as a function of pH and fulvic acid concentration. The results...

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Main Authors: Lei Chen, Xianjin Yu, Zengdian Zhao, Yunhui Dong
Format: Article
Language:English
Published: SAGE Publishing 2006-05-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/026361706779319616
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author Lei Chen
Xianjin Yu
Zengdian Zhao
Yunhui Dong
author_facet Lei Chen
Xianjin Yu
Zengdian Zhao
Yunhui Dong
author_sort Lei Chen
collection DOAJ
description Thorium was considered as a chemical analogue of other tetravalent actinides. The sorption of Th(IV) ions onto montmorillonite and its cross-linked counterpart in the presence/absence of fulvic acid was investigated via a batch technique as a function of pH and fulvic acid concentration. The results obtained indicate that the sorption of Th(IV) ions was strongly dependent on the pH value of its solution, with the presence of fulvic acid enhancing such sorption at low pH values. It was also found that the sorption of Th(IV) ions was dependent on the ionic strength. Cross-linked montmorillonite was found to be a suitable candidate for the sorption and pre-concentration of Th(IV) ions from large volumes of liquid solution. Surface complexation rather than cation exchange mainly contributes to the sorption of Th(IV) ions onto montmorillonite.
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series Adsorption Science & Technology
spelling doaj-art-fa7e2df2d4d44039a768ce8b950b0d382025-01-03T00:10:25ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382006-05-012410.1260/026361706779319616The Sorption of Th(IV) Ions onto Montmorillonite: The Effect of pH, Ionic Strength and Fulvic AcidLei ChenXianjin YuZengdian ZhaoYunhui DongThorium was considered as a chemical analogue of other tetravalent actinides. The sorption of Th(IV) ions onto montmorillonite and its cross-linked counterpart in the presence/absence of fulvic acid was investigated via a batch technique as a function of pH and fulvic acid concentration. The results obtained indicate that the sorption of Th(IV) ions was strongly dependent on the pH value of its solution, with the presence of fulvic acid enhancing such sorption at low pH values. It was also found that the sorption of Th(IV) ions was dependent on the ionic strength. Cross-linked montmorillonite was found to be a suitable candidate for the sorption and pre-concentration of Th(IV) ions from large volumes of liquid solution. Surface complexation rather than cation exchange mainly contributes to the sorption of Th(IV) ions onto montmorillonite.https://doi.org/10.1260/026361706779319616
spellingShingle Lei Chen
Xianjin Yu
Zengdian Zhao
Yunhui Dong
The Sorption of Th(IV) Ions onto Montmorillonite: The Effect of pH, Ionic Strength and Fulvic Acid
Adsorption Science & Technology
title The Sorption of Th(IV) Ions onto Montmorillonite: The Effect of pH, Ionic Strength and Fulvic Acid
title_full The Sorption of Th(IV) Ions onto Montmorillonite: The Effect of pH, Ionic Strength and Fulvic Acid
title_fullStr The Sorption of Th(IV) Ions onto Montmorillonite: The Effect of pH, Ionic Strength and Fulvic Acid
title_full_unstemmed The Sorption of Th(IV) Ions onto Montmorillonite: The Effect of pH, Ionic Strength and Fulvic Acid
title_short The Sorption of Th(IV) Ions onto Montmorillonite: The Effect of pH, Ionic Strength and Fulvic Acid
title_sort sorption of th iv ions onto montmorillonite the effect of ph ionic strength and fulvic acid
url https://doi.org/10.1260/026361706779319616
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