Adsorption of Acid Blue 129 from Aqueous Solutions onto Raw and Surfactant-Modified Bentonite: Application of Temperature-Dependent Forms of Adsorption Isotherms

Modification of raw bentonite from Ponorogo, East Java, Indonesia by microwave irradiation using cetyltrimethylammonium bromide (CTAB) was studied. The adsorption capabilities of raw bentonite and its modified form were examined through their use in the removal of Acid Blue 129 from aqueous solution...

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Main Authors: Yesi, Fiona Patricia Sisnandy, Yi-Hsu Ju, Felycia Edi Soetaredjo, Suryadi Ismadji
Format: Article
Language:English
Published: SAGE Publishing 2010-12-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263-6174.28.10.847
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author Yesi
Fiona Patricia Sisnandy
Yi-Hsu Ju
Felycia Edi Soetaredjo
Suryadi Ismadji
author_facet Yesi
Fiona Patricia Sisnandy
Yi-Hsu Ju
Felycia Edi Soetaredjo
Suryadi Ismadji
author_sort Yesi
collection DOAJ
description Modification of raw bentonite from Ponorogo, East Java, Indonesia by microwave irradiation using cetyltrimethylammonium bromide (CTAB) was studied. The adsorption capabilities of raw bentonite and its modified form were examined through their use in the removal of Acid Blue 129 from aqueous solution. The adsorption isotherm and kinetic experiments were conducted at four temperatures (25, 30, 40 and 50 °C). The fitting of the corresponding experimental data was tested using the temperature-dependent forms of the Langmuir, Freundlich, Sips and Toth equations. The Sips equation gave a better representation of the adsorption data, together with reasonable values of the fitted parameters. Two well-known kinetic models, the pseudo-first- and pseudo-second-order, were used to correlate the adsorption kinetic data, with the pseudo-first-order model giving the better results. Both physical and chemical adsorption mechanisms occurred during the adsorption process, with the main controlling mechanism being physical adsorption.
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institution Kabale University
issn 0263-6174
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publishDate 2010-12-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-e9e2b2a55a5a4940b38a5b2947d971932025-01-03T01:19:32ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382010-12-012810.1260/0263-6174.28.10.847Adsorption of Acid Blue 129 from Aqueous Solutions onto Raw and Surfactant-Modified Bentonite: Application of Temperature-Dependent Forms of Adsorption Isotherms Yesi0Fiona Patricia Sisnandy1Yi-Hsu Ju2Felycia Edi Soetaredjo3Suryadi Ismadji4 Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia Department of Chemical Engineering, National Taiwan University of Science and Technology, 43, sec. 4 Keelung Rd., Taipei, 106 Taiwan Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, IndonesiaModification of raw bentonite from Ponorogo, East Java, Indonesia by microwave irradiation using cetyltrimethylammonium bromide (CTAB) was studied. The adsorption capabilities of raw bentonite and its modified form were examined through their use in the removal of Acid Blue 129 from aqueous solution. The adsorption isotherm and kinetic experiments were conducted at four temperatures (25, 30, 40 and 50 °C). The fitting of the corresponding experimental data was tested using the temperature-dependent forms of the Langmuir, Freundlich, Sips and Toth equations. The Sips equation gave a better representation of the adsorption data, together with reasonable values of the fitted parameters. Two well-known kinetic models, the pseudo-first- and pseudo-second-order, were used to correlate the adsorption kinetic data, with the pseudo-first-order model giving the better results. Both physical and chemical adsorption mechanisms occurred during the adsorption process, with the main controlling mechanism being physical adsorption.https://doi.org/10.1260/0263-6174.28.10.847
spellingShingle Yesi
Fiona Patricia Sisnandy
Yi-Hsu Ju
Felycia Edi Soetaredjo
Suryadi Ismadji
Adsorption of Acid Blue 129 from Aqueous Solutions onto Raw and Surfactant-Modified Bentonite: Application of Temperature-Dependent Forms of Adsorption Isotherms
Adsorption Science & Technology
title Adsorption of Acid Blue 129 from Aqueous Solutions onto Raw and Surfactant-Modified Bentonite: Application of Temperature-Dependent Forms of Adsorption Isotherms
title_full Adsorption of Acid Blue 129 from Aqueous Solutions onto Raw and Surfactant-Modified Bentonite: Application of Temperature-Dependent Forms of Adsorption Isotherms
title_fullStr Adsorption of Acid Blue 129 from Aqueous Solutions onto Raw and Surfactant-Modified Bentonite: Application of Temperature-Dependent Forms of Adsorption Isotherms
title_full_unstemmed Adsorption of Acid Blue 129 from Aqueous Solutions onto Raw and Surfactant-Modified Bentonite: Application of Temperature-Dependent Forms of Adsorption Isotherms
title_short Adsorption of Acid Blue 129 from Aqueous Solutions onto Raw and Surfactant-Modified Bentonite: Application of Temperature-Dependent Forms of Adsorption Isotherms
title_sort adsorption of acid blue 129 from aqueous solutions onto raw and surfactant modified bentonite application of temperature dependent forms of adsorption isotherms
url https://doi.org/10.1260/0263-6174.28.10.847
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