Structural and Morphological Characterization of MEH-PPV/Ag Composite

In this study, spin coating was used to prepare thin films of poly (2-methoxy-5-(2-ethylhexyloxy)-1, 4-phenylene vinylene) and silver (MEH-PPV/Ag) in this study. The physical characteristics of MEH-PPV/Ag thin films with various weight ratios (0.01, 0.02, 0.03, and 0.04%) were investigated by Fouri...

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Main Authors: Suha Ahmad Jawad, Mustafa Mohammed Ali Hussein
Format: Article
Language:English
Published: University of Baghdad 2024-03-01
Series:Iraqi Journal of Physics
Subjects:
Online Access:https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/1131
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author Suha Ahmad Jawad
Mustafa Mohammed Ali Hussein
author_facet Suha Ahmad Jawad
Mustafa Mohammed Ali Hussein
author_sort Suha Ahmad Jawad
collection DOAJ
description In this study, spin coating was used to prepare thin films of poly (2-methoxy-5-(2-ethylhexyloxy)-1, 4-phenylene vinylene) and silver (MEH-PPV/Ag) in this study. The physical characteristics of MEH-PPV/Ag thin films with various weight ratios (0.01, 0.02, 0.03, and 0.04%) were investigated by Fourier-transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), X-ray diffraction analysis (XRD), and thermal testing. FTIR analysis showed that there were occurrences of the polymer's predicted chemical bonds. AFM tests show that when different amounts of silver are added to a polymer matrix, the film's surface roughness (root mean square) goes up from an average of 83.51 to 511.3 nm. FE-SEM analysis showed that a pure sample of the polymer formed evenly. However, when different amounts of Ag were added, clear balls or circles formed, showing the energy of mixing between the MEH-PPV and Ag. As silver addition transformed the polymer from amorphous to polycrystalline, XRD analysis revealed both phases. In tests comparing pure MEH-PPV to MEH-PPV/Ag, the polymer containing silver showed higher thermal conductivity.
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institution Kabale University
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language English
publishDate 2024-03-01
publisher University of Baghdad
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series Iraqi Journal of Physics
spelling doaj-art-e588c1a075fc4c93a43fbdaf8c2e5a9b2024-12-23T08:27:23ZengUniversity of BaghdadIraqi Journal of Physics2070-40032664-55482024-03-0122110.30723/ijp.v22i1.1131 Structural and Morphological Characterization of MEH-PPV/Ag CompositeSuha Ahmad Jawad0Mustafa Mohammed Ali Hussein1Department of Physics, College of Science, University of Baghdad, Baghdad, IraqDepartment of Physics, College of Science, University of Baghdad, Baghdad, Iraq In this study, spin coating was used to prepare thin films of poly (2-methoxy-5-(2-ethylhexyloxy)-1, 4-phenylene vinylene) and silver (MEH-PPV/Ag) in this study. The physical characteristics of MEH-PPV/Ag thin films with various weight ratios (0.01, 0.02, 0.03, and 0.04%) were investigated by Fourier-transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), X-ray diffraction analysis (XRD), and thermal testing. FTIR analysis showed that there were occurrences of the polymer's predicted chemical bonds. AFM tests show that when different amounts of silver are added to a polymer matrix, the film's surface roughness (root mean square) goes up from an average of 83.51 to 511.3 nm. FE-SEM analysis showed that a pure sample of the polymer formed evenly. However, when different amounts of Ag were added, clear balls or circles formed, showing the energy of mixing between the MEH-PPV and Ag. As silver addition transformed the polymer from amorphous to polycrystalline, XRD analysis revealed both phases. In tests comparing pure MEH-PPV to MEH-PPV/Ag, the polymer containing silver showed higher thermal conductivity. https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/1131MEH-PPV/Ag Thin Films FTIRFE-SEMXRDThermal Conductivity
spellingShingle Suha Ahmad Jawad
Mustafa Mohammed Ali Hussein
Structural and Morphological Characterization of MEH-PPV/Ag Composite
Iraqi Journal of Physics
MEH-PPV/Ag Thin Films
FTIR
FE-SEM
XRD
Thermal Conductivity
title Structural and Morphological Characterization of MEH-PPV/Ag Composite
title_full Structural and Morphological Characterization of MEH-PPV/Ag Composite
title_fullStr Structural and Morphological Characterization of MEH-PPV/Ag Composite
title_full_unstemmed Structural and Morphological Characterization of MEH-PPV/Ag Composite
title_short Structural and Morphological Characterization of MEH-PPV/Ag Composite
title_sort structural and morphological characterization of meh ppv ag composite
topic MEH-PPV/Ag Thin Films
FTIR
FE-SEM
XRD
Thermal Conductivity
url https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/1131
work_keys_str_mv AT suhaahmadjawad structuralandmorphologicalcharacterizationofmehppvagcomposite
AT mustafamohammedalihussein structuralandmorphologicalcharacterizationofmehppvagcomposite