Catalytic Behavior of NHC–Silver Complexes in the Carboxylation of Terminal Alkynes with CO<sub>2</sub>

Catalytic Behavior of NHC–Silver Complexes in the Carboxylation of Terminal Alkynes with CO<sub>2</sub>

A number of N-heterocyclic carbene–silver compounds (NHCs)AgX were tested in the direct carboxylation of terminal alkynes using carbon dioxide as the C1 carbon feedstock. The reactions proceed at a pressure of 1 atm of CO<sub>2</sub> at room temperature, in the presence of Cs<sub>2...

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Bibliographic Details
Main Authors: Assunta D’Amato, Marco Sirignano, Francesco Viceconte, Pasquale Longo, Annaluisa Mariconda
Format: Article
Language:English
Published: MDPI AG 2024-10-01
Series:Inorganics
Subjects:
carboxylation
terminal alkynes
CO<sub>2</sub>
propiolic acids
NHC silver complexes
Online Access:https://www.mdpi.com/2304-6740/12/11/283
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