A STUDY OF THE SILYLATION REACTION OF IMINES WITH TRIMETHYLCHLOROSILANE IN THE PRESENCE OF LITHIUM

A mixture oftrimethylchlorosilane (TMS-Cl), lithium and tetrahydrofuran (THF) reacts with imines to produce disilyl compound by addition of two trimethylsilyl (TMS) groups to the double bond of the imine. On hydrolysis the TMS on nitrogen is substituted by hydrogen and yields ? -silylamine. In the...

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Bibliographic Details
Format: Article
Language:English
Published: University of Tehran 1993-09-01
Series:Journal of Sciences, Islamic Republic of Iran
Online Access:https://jsciences.ut.ac.ir/article_31557_705dd8acba00082e36fc4838b6986659.pdf
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