A Facile Method to Incorporate Di‐Dopant Elements (F and Sb) into Crystalline Mesoporous Tin Dioxide Nano Powder at Ambient Temperature and Pressure

Abstract A simple two step synthetic method for di‐doped crystalline mesoporous tin dioxide powder containing antimony and fluoride at ambient pressure and temperature has been developed. This approach produced materials with high surface areas and improved electrical and optoelectrical conductance....

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Main Authors: Tariq Aqeel, Heather F. Greer
Format: Article
Language:English
Published: Wiley-VCH 2025-01-01
Series:ChemistryOpen
Subjects:
Online Access:https://doi.org/10.1002/open.202400096
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author Tariq Aqeel
Heather F. Greer
author_facet Tariq Aqeel
Heather F. Greer
author_sort Tariq Aqeel
collection DOAJ
description Abstract A simple two step synthetic method for di‐doped crystalline mesoporous tin dioxide powder containing antimony and fluoride at ambient pressure and temperature has been developed. This approach produced materials with high surface areas and improved electrical and optoelectrical conductance. The two dopant elements; antimony and fluoride were introduced to tin dioxide by two approaches. Both approaches produced mesoporous tin dioxide with antimony and fluoride that are integrated in the framework. The structures of these materials are analyzed by powder X‐ray diffraction, N2 sorption analysis, transmission electron microscopy, energy dispersive X‐ray spectroscopy and X‐ray photoelectron spectroscopy. The conductance of the materials improved by factor of 13–34 compared to undoped mesoporous tin dioxide. The effect of the di‐doped elements on structure, conductance and optoelectronic properties of these materials are discussed in this paper.
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spelling doaj-art-b68a460c937d46f3bafb5cb01d6f14792025-01-11T07:54:10ZengWiley-VCHChemistryOpen2191-13632025-01-01141n/an/a10.1002/open.202400096A Facile Method to Incorporate Di‐Dopant Elements (F and Sb) into Crystalline Mesoporous Tin Dioxide Nano Powder at Ambient Temperature and PressureTariq Aqeel0Heather F. Greer1Department of Science College of basic education The Public Authority for Applied Education and Training (PAAET) P.O. Box 23167 Safat 13092 KuwaitYusuf Hamied Department of Chemistry University of Cambridge Cambridge CB2 1EW UKAbstract A simple two step synthetic method for di‐doped crystalline mesoporous tin dioxide powder containing antimony and fluoride at ambient pressure and temperature has been developed. This approach produced materials with high surface areas and improved electrical and optoelectrical conductance. The two dopant elements; antimony and fluoride were introduced to tin dioxide by two approaches. Both approaches produced mesoporous tin dioxide with antimony and fluoride that are integrated in the framework. The structures of these materials are analyzed by powder X‐ray diffraction, N2 sorption analysis, transmission electron microscopy, energy dispersive X‐ray spectroscopy and X‐ray photoelectron spectroscopy. The conductance of the materials improved by factor of 13–34 compared to undoped mesoporous tin dioxide. The effect of the di‐doped elements on structure, conductance and optoelectronic properties of these materials are discussed in this paper.https://doi.org/10.1002/open.202400096MesoporousTin dioxideFluorideAntimonyOptoelectronic conductance
spellingShingle Tariq Aqeel
Heather F. Greer
A Facile Method to Incorporate Di‐Dopant Elements (F and Sb) into Crystalline Mesoporous Tin Dioxide Nano Powder at Ambient Temperature and Pressure
ChemistryOpen
Mesoporous
Tin dioxide
Fluoride
Antimony
Optoelectronic conductance
title A Facile Method to Incorporate Di‐Dopant Elements (F and Sb) into Crystalline Mesoporous Tin Dioxide Nano Powder at Ambient Temperature and Pressure
title_full A Facile Method to Incorporate Di‐Dopant Elements (F and Sb) into Crystalline Mesoporous Tin Dioxide Nano Powder at Ambient Temperature and Pressure
title_fullStr A Facile Method to Incorporate Di‐Dopant Elements (F and Sb) into Crystalline Mesoporous Tin Dioxide Nano Powder at Ambient Temperature and Pressure
title_full_unstemmed A Facile Method to Incorporate Di‐Dopant Elements (F and Sb) into Crystalline Mesoporous Tin Dioxide Nano Powder at Ambient Temperature and Pressure
title_short A Facile Method to Incorporate Di‐Dopant Elements (F and Sb) into Crystalline Mesoporous Tin Dioxide Nano Powder at Ambient Temperature and Pressure
title_sort facile method to incorporate di dopant elements f and sb into crystalline mesoporous tin dioxide nano powder at ambient temperature and pressure
topic Mesoporous
Tin dioxide
Fluoride
Antimony
Optoelectronic conductance
url https://doi.org/10.1002/open.202400096
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