Experimental Assessment of Magnetic Nanofluid Injection in High-Salinity and Heavy-Crude-Saturated Sandstone: Mitigation of Formation Damage

The depletion of conventional oil reserves has intensified the search for enhanced oil recovery (EOR) techniques. Recently, nanoparticle research has focused on graphene oxide-based materials, revealing a critical challenge in their practical application. Laboratory investigations have consistently...

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Main Authors: Jimena Lizeth Gómez-Delgado, Nelson Gutierrez-Niño, Luis Felipe Carrillo-Moreno, Raúl Andres Martínez-López, Nicolás Santos-Santos, Enrique Mejía-Ospino
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Energies
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Online Access:https://www.mdpi.com/1996-1073/18/1/212
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author Jimena Lizeth Gómez-Delgado
Nelson Gutierrez-Niño
Luis Felipe Carrillo-Moreno
Raúl Andres Martínez-López
Nicolás Santos-Santos
Enrique Mejía-Ospino
author_facet Jimena Lizeth Gómez-Delgado
Nelson Gutierrez-Niño
Luis Felipe Carrillo-Moreno
Raúl Andres Martínez-López
Nicolás Santos-Santos
Enrique Mejía-Ospino
author_sort Jimena Lizeth Gómez-Delgado
collection DOAJ
description The depletion of conventional oil reserves has intensified the search for enhanced oil recovery (EOR) techniques. Recently, nanoparticle research has focused on graphene oxide-based materials, revealing a critical challenge in their practical application. Laboratory investigations have consistently demonstrated that these nanoparticles have significant potential for formation damage, a critical limitation that substantially constrains their potential field implementation. This research addresses a critical challenge in EOR: developing magnetic graphene oxide nanoparticles (MGONs) that can traverse rock formations without causing formation damage. MGONs were synthesized and stabilized in formation brine with a high total dissolved solids (TDS) content with a xanthan gum polymer. Two coreflooding experiments were conducted on sandstone cores. The first experiment on high-permeability sandstone (843 mD) showed no formation damage; instead, permeability increased to 935 mD after MGON injection. Irreducible water saturation (S<sub>wirr</sub>) and residual oil saturation (S<sub>or</sub>) were 25.1% and 31.5%, respectively. The second experiment on lower-permeability rock (231.3 mD) evaluated nanoparticle retention. The results showed that 0.09511 mg of MGONs was adsorbed per gram of rock under dynamic conditions. Iron concentration in effluents stabilized after 3 pore volumes, indicating steady-state adsorption. The successful synthesis, stability in high-TDS brine, favorable interfacial properties, and positive effects observed in coreflooding experiments collectively highlight MGONs’ potential as a viable solution for enhancing oil recovery in challenging reservoirs, without causing formation damage.
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spelling doaj-art-b50794bca306485090368320f8e7cb452025-01-10T13:17:26ZengMDPI AGEnergies1996-10732025-01-0118121210.3390/en18010212Experimental Assessment of Magnetic Nanofluid Injection in High-Salinity and Heavy-Crude-Saturated Sandstone: Mitigation of Formation DamageJimena Lizeth Gómez-Delgado0Nelson Gutierrez-Niño1Luis Felipe Carrillo-Moreno2Raúl Andres Martínez-López3Nicolás Santos-Santos4Enrique Mejía-Ospino5Grupo de Investigación en Tomografía (GIT), Universidad Industrial de Santander, 680002 Bucaramanga, ColombiaLaboratorio de Espectroscopia Atómica y Molecular (LEAM), Universidad Industrial de Santander, 680002 Bucaramanga, ColombiaGrupo de Investigación en Tomografía (GIT), Universidad Industrial de Santander, 680002 Bucaramanga, ColombiaGrupo de Investigación en Tomografía (GIT), Universidad Industrial de Santander, 680002 Bucaramanga, ColombiaGrupo de Investigación en Tomografía (GIT), Universidad Industrial de Santander, 680002 Bucaramanga, ColombiaGrupo de Investigación en Tomografía (GIT), Universidad Industrial de Santander, 680002 Bucaramanga, ColombiaThe depletion of conventional oil reserves has intensified the search for enhanced oil recovery (EOR) techniques. Recently, nanoparticle research has focused on graphene oxide-based materials, revealing a critical challenge in their practical application. Laboratory investigations have consistently demonstrated that these nanoparticles have significant potential for formation damage, a critical limitation that substantially constrains their potential field implementation. This research addresses a critical challenge in EOR: developing magnetic graphene oxide nanoparticles (MGONs) that can traverse rock formations without causing formation damage. MGONs were synthesized and stabilized in formation brine with a high total dissolved solids (TDS) content with a xanthan gum polymer. Two coreflooding experiments were conducted on sandstone cores. The first experiment on high-permeability sandstone (843 mD) showed no formation damage; instead, permeability increased to 935 mD after MGON injection. Irreducible water saturation (S<sub>wirr</sub>) and residual oil saturation (S<sub>or</sub>) were 25.1% and 31.5%, respectively. The second experiment on lower-permeability rock (231.3 mD) evaluated nanoparticle retention. The results showed that 0.09511 mg of MGONs was adsorbed per gram of rock under dynamic conditions. Iron concentration in effluents stabilized after 3 pore volumes, indicating steady-state adsorption. The successful synthesis, stability in high-TDS brine, favorable interfacial properties, and positive effects observed in coreflooding experiments collectively highlight MGONs’ potential as a viable solution for enhancing oil recovery in challenging reservoirs, without causing formation damage.https://www.mdpi.com/1996-1073/18/1/212magnetic graphene oxideformation damagenanofluidheavy crude oilcoreflooding
spellingShingle Jimena Lizeth Gómez-Delgado
Nelson Gutierrez-Niño
Luis Felipe Carrillo-Moreno
Raúl Andres Martínez-López
Nicolás Santos-Santos
Enrique Mejía-Ospino
Experimental Assessment of Magnetic Nanofluid Injection in High-Salinity and Heavy-Crude-Saturated Sandstone: Mitigation of Formation Damage
Energies
magnetic graphene oxide
formation damage
nanofluid
heavy crude oil
coreflooding
title Experimental Assessment of Magnetic Nanofluid Injection in High-Salinity and Heavy-Crude-Saturated Sandstone: Mitigation of Formation Damage
title_full Experimental Assessment of Magnetic Nanofluid Injection in High-Salinity and Heavy-Crude-Saturated Sandstone: Mitigation of Formation Damage
title_fullStr Experimental Assessment of Magnetic Nanofluid Injection in High-Salinity and Heavy-Crude-Saturated Sandstone: Mitigation of Formation Damage
title_full_unstemmed Experimental Assessment of Magnetic Nanofluid Injection in High-Salinity and Heavy-Crude-Saturated Sandstone: Mitigation of Formation Damage
title_short Experimental Assessment of Magnetic Nanofluid Injection in High-Salinity and Heavy-Crude-Saturated Sandstone: Mitigation of Formation Damage
title_sort experimental assessment of magnetic nanofluid injection in high salinity and heavy crude saturated sandstone mitigation of formation damage
topic magnetic graphene oxide
formation damage
nanofluid
heavy crude oil
coreflooding
url https://www.mdpi.com/1996-1073/18/1/212
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