Adsorption of paraquat and pirimiphos-methyl by montmorillonite modified with tetradecylammonium chloride and intragallery templating method
Adsorption of paraquat and pirimiphos-methyl in water was performed on four adsorbents including montmorillonite (Mt), organoclay (TDA-Mt) from intercalation of Mt with tetradecylammonium chloride, and mesoporous Mt from intragallery templating method (with and without Ti addition). The adsorbents w...
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| Format: | Article |
| Language: | English |
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SAGE Publishing
2017-05-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1177/0263617416677351 |
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| author | Chalermpan Keawkumay Suriyan Rakmae Wina Rongchapo Nitinat Suppakarn Sanchai Prayoonpokarach Jatuporn Wittayakun |
| author_facet | Chalermpan Keawkumay Suriyan Rakmae Wina Rongchapo Nitinat Suppakarn Sanchai Prayoonpokarach Jatuporn Wittayakun |
| author_sort | Chalermpan Keawkumay |
| collection | DOAJ |
| description | Adsorption of paraquat and pirimiphos-methyl in water was performed on four adsorbents including montmorillonite (Mt), organoclay (TDA-Mt) from intercalation of Mt with tetradecylammonium chloride, and mesoporous Mt from intragallery templating method (with and without Ti addition). The adsorbents were characterized by X-ray diffraction, N 2 adsorption–desorption, and transmission electron microscopy. Paraquat adsorption isotherms followed Langmuir model and the adsorption capacity was as follows: TDA-Mt > Mt > mesoporous Ti-Mt > mesoporous Mt. The adsorption mechanism on TDA-Mt and Mt might be via ion exchange. The adsorption on mesoporous samples was on the external surface with negative charge. The presence of Ti enhanced the adsorption capacity. Pirimiphos-methyl adsorbed on negative charge of the external surface of Mt samples. The adsorbed amount increased with the initial concentration due to a strong intermolecular interaction. |
| format | Article |
| id | doaj-art-a72fe1b061d34d008cae4adb71cc0ffc |
| institution | Kabale University |
| issn | 0263-6174 2048-4038 |
| language | English |
| publishDate | 2017-05-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj-art-a72fe1b061d34d008cae4adb71cc0ffc2025-01-03T01:24:47ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382017-05-013510.1177/0263617416677351Adsorption of paraquat and pirimiphos-methyl by montmorillonite modified with tetradecylammonium chloride and intragallery templating methodChalermpan KeawkumaySuriyan RakmaeWina RongchapoNitinat SuppakarnSanchai PrayoonpokarachJatuporn WittayakunAdsorption of paraquat and pirimiphos-methyl in water was performed on four adsorbents including montmorillonite (Mt), organoclay (TDA-Mt) from intercalation of Mt with tetradecylammonium chloride, and mesoporous Mt from intragallery templating method (with and without Ti addition). The adsorbents were characterized by X-ray diffraction, N 2 adsorption–desorption, and transmission electron microscopy. Paraquat adsorption isotherms followed Langmuir model and the adsorption capacity was as follows: TDA-Mt > Mt > mesoporous Ti-Mt > mesoporous Mt. The adsorption mechanism on TDA-Mt and Mt might be via ion exchange. The adsorption on mesoporous samples was on the external surface with negative charge. The presence of Ti enhanced the adsorption capacity. Pirimiphos-methyl adsorbed on negative charge of the external surface of Mt samples. The adsorbed amount increased with the initial concentration due to a strong intermolecular interaction.https://doi.org/10.1177/0263617416677351 |
| spellingShingle | Chalermpan Keawkumay Suriyan Rakmae Wina Rongchapo Nitinat Suppakarn Sanchai Prayoonpokarach Jatuporn Wittayakun Adsorption of paraquat and pirimiphos-methyl by montmorillonite modified with tetradecylammonium chloride and intragallery templating method Adsorption Science & Technology |
| title | Adsorption of paraquat and pirimiphos-methyl by montmorillonite modified with tetradecylammonium chloride and intragallery templating method |
| title_full | Adsorption of paraquat and pirimiphos-methyl by montmorillonite modified with tetradecylammonium chloride and intragallery templating method |
| title_fullStr | Adsorption of paraquat and pirimiphos-methyl by montmorillonite modified with tetradecylammonium chloride and intragallery templating method |
| title_full_unstemmed | Adsorption of paraquat and pirimiphos-methyl by montmorillonite modified with tetradecylammonium chloride and intragallery templating method |
| title_short | Adsorption of paraquat and pirimiphos-methyl by montmorillonite modified with tetradecylammonium chloride and intragallery templating method |
| title_sort | adsorption of paraquat and pirimiphos methyl by montmorillonite modified with tetradecylammonium chloride and intragallery templating method |
| url | https://doi.org/10.1177/0263617416677351 |
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