Can the Artificial Release of Fluorinated Gases Offset Global Cooling Due to Supervolcanic Eruptions?

Large volcanic eruptions, such as the prehistoric Yellowstone eruption, induce abrupt global cooling—by some estimates at a rate of ~1 °C/year, lasting for more than a decade. An abrupt global cooling of several °C—even if only lasting a few years—would present immediate, drastic stress on biodivers...

Full description

Saved in:
Bibliographic Details
Main Authors: Yangyang Xu, Nathanael P. Ribar, Jeffrey Sachnik, Gunnar W. Schade, Andrew John Lockley, Yi Ge Zhang, Pengfei Yu, Jianxin Hu, Guus J. M. Velders
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Atmosphere
Subjects:
Online Access:https://www.mdpi.com/2073-4433/15/11/1322
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1846154412538462208
author Yangyang Xu
Nathanael P. Ribar
Jeffrey Sachnik
Gunnar W. Schade
Andrew John Lockley
Yi Ge Zhang
Pengfei Yu
Jianxin Hu
Guus J. M. Velders
author_facet Yangyang Xu
Nathanael P. Ribar
Jeffrey Sachnik
Gunnar W. Schade
Andrew John Lockley
Yi Ge Zhang
Pengfei Yu
Jianxin Hu
Guus J. M. Velders
author_sort Yangyang Xu
collection DOAJ
description Large volcanic eruptions, such as the prehistoric Yellowstone eruption, induce abrupt global cooling—by some estimates at a rate of ~1 °C/year, lasting for more than a decade. An abrupt global cooling of several °C—even if only lasting a few years—would present immediate, drastic stress on biodiversity and food production. This cooling poses a global catastrophic risk to human society beyond the immediate and direct impact of eruptions. Using a simple climate model, this paper discusses the possibility of counteracting large volcanic cooling with the intentional release of greenhouse gases. Longer-lived compounds (e.g., CO<sub>2</sub> and CH<sub>4</sub>) are unsuitable for this purpose, but selected fluorinated gases (F-gases), either individually or in combinations, could be released at gigaton scale to offset large volcanic cooling substantially. We identify candidate F-gases (e.g., C<sub>4</sub>F<sub>6</sub> and CH<sub>3</sub>F) and derive radiative and chemical properties of ‘ideal’ compounds matching specific cooling events. Geophysical constraints on manufacturing and stockpiling due to mineral availability are considered, alongside technical and economic implications based on present-day market assumptions. The effects and uncertainty due to atmospheric chemistry related to aerosol injection, F-gases release, and solar dimming are discussed in the context of large volcanic perturbation. The caveats and future steps using more complex chemistry–climate models are discussed. Despite the speculative nature of the magnitude and composition of F-gases, our conceptual analysis has implications for testing the possibility of mitigating certain global catastrophic cooling risks (e.g., nuclear winter, asteroid impact, and glacier transition) via intentional intervention.
format Article
id doaj-art-a664c44d711c4e66907e4e9a420e1ae5
institution Kabale University
issn 2073-4433
language English
publishDate 2024-11-01
publisher MDPI AG
record_format Article
series Atmosphere
spelling doaj-art-a664c44d711c4e66907e4e9a420e1ae52024-11-26T17:50:22ZengMDPI AGAtmosphere2073-44332024-11-011511132210.3390/atmos15111322Can the Artificial Release of Fluorinated Gases Offset Global Cooling Due to Supervolcanic Eruptions?Yangyang Xu0Nathanael P. Ribar1Jeffrey Sachnik2Gunnar W. Schade3Andrew John Lockley4Yi Ge Zhang5Pengfei Yu6Jianxin Hu7Guus J. M. Velders8Department of Atmospheric Sciences, Texas A&M University, College Station, TX 77843, USADepartment of Atmospheric Science, University of Wyoming, Laramie, WY 82071, USADepartment of Atmospheric Sciences, Texas A&M University, College Station, TX 77843, USADepartment of Atmospheric Sciences, Texas A&M University, College Station, TX 77843, USAIndependent Researcher, London, UKGuangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, ChinaInstitute for Environmental and Climate Research, Jinan University, Guangzhou 511496, ChinaDepartment of Environmental Science, Peking University, Beijing 100871, ChinaNational Institute for Public Health and the Environment (RIVM), Antonie van Leeuwenhoeklaan 9, 3721 MA Bilthoven, The NetherlandsLarge volcanic eruptions, such as the prehistoric Yellowstone eruption, induce abrupt global cooling—by some estimates at a rate of ~1 °C/year, lasting for more than a decade. An abrupt global cooling of several °C—even if only lasting a few years—would present immediate, drastic stress on biodiversity and food production. This cooling poses a global catastrophic risk to human society beyond the immediate and direct impact of eruptions. Using a simple climate model, this paper discusses the possibility of counteracting large volcanic cooling with the intentional release of greenhouse gases. Longer-lived compounds (e.g., CO<sub>2</sub> and CH<sub>4</sub>) are unsuitable for this purpose, but selected fluorinated gases (F-gases), either individually or in combinations, could be released at gigaton scale to offset large volcanic cooling substantially. We identify candidate F-gases (e.g., C<sub>4</sub>F<sub>6</sub> and CH<sub>3</sub>F) and derive radiative and chemical properties of ‘ideal’ compounds matching specific cooling events. Geophysical constraints on manufacturing and stockpiling due to mineral availability are considered, alongside technical and economic implications based on present-day market assumptions. The effects and uncertainty due to atmospheric chemistry related to aerosol injection, F-gases release, and solar dimming are discussed in the context of large volcanic perturbation. The caveats and future steps using more complex chemistry–climate models are discussed. Despite the speculative nature of the magnitude and composition of F-gases, our conceptual analysis has implications for testing the possibility of mitigating certain global catastrophic cooling risks (e.g., nuclear winter, asteroid impact, and glacier transition) via intentional intervention.https://www.mdpi.com/2073-4433/15/11/1322geoengineeringcounter-geoengineeringsimple climate modelsupervolcanic eruptionsfluorinated gases
spellingShingle Yangyang Xu
Nathanael P. Ribar
Jeffrey Sachnik
Gunnar W. Schade
Andrew John Lockley
Yi Ge Zhang
Pengfei Yu
Jianxin Hu
Guus J. M. Velders
Can the Artificial Release of Fluorinated Gases Offset Global Cooling Due to Supervolcanic Eruptions?
Atmosphere
geoengineering
counter-geoengineering
simple climate model
supervolcanic eruptions
fluorinated gases
title Can the Artificial Release of Fluorinated Gases Offset Global Cooling Due to Supervolcanic Eruptions?
title_full Can the Artificial Release of Fluorinated Gases Offset Global Cooling Due to Supervolcanic Eruptions?
title_fullStr Can the Artificial Release of Fluorinated Gases Offset Global Cooling Due to Supervolcanic Eruptions?
title_full_unstemmed Can the Artificial Release of Fluorinated Gases Offset Global Cooling Due to Supervolcanic Eruptions?
title_short Can the Artificial Release of Fluorinated Gases Offset Global Cooling Due to Supervolcanic Eruptions?
title_sort can the artificial release of fluorinated gases offset global cooling due to supervolcanic eruptions
topic geoengineering
counter-geoengineering
simple climate model
supervolcanic eruptions
fluorinated gases
url https://www.mdpi.com/2073-4433/15/11/1322
work_keys_str_mv AT yangyangxu cantheartificialreleaseoffluorinatedgasesoffsetglobalcoolingduetosupervolcaniceruptions
AT nathanaelpribar cantheartificialreleaseoffluorinatedgasesoffsetglobalcoolingduetosupervolcaniceruptions
AT jeffreysachnik cantheartificialreleaseoffluorinatedgasesoffsetglobalcoolingduetosupervolcaniceruptions
AT gunnarwschade cantheartificialreleaseoffluorinatedgasesoffsetglobalcoolingduetosupervolcaniceruptions
AT andrewjohnlockley cantheartificialreleaseoffluorinatedgasesoffsetglobalcoolingduetosupervolcaniceruptions
AT yigezhang cantheartificialreleaseoffluorinatedgasesoffsetglobalcoolingduetosupervolcaniceruptions
AT pengfeiyu cantheartificialreleaseoffluorinatedgasesoffsetglobalcoolingduetosupervolcaniceruptions
AT jianxinhu cantheartificialreleaseoffluorinatedgasesoffsetglobalcoolingduetosupervolcaniceruptions
AT guusjmvelders cantheartificialreleaseoffluorinatedgasesoffsetglobalcoolingduetosupervolcaniceruptions