Unexpected XPS Binding Energy Observations Further Highlighted by DFT Calculations of Ruthenocene-Containing [Ir<sup>III</sup>(ppy)<sub>2</sub>(RCOCHCORc)] Complexes: Cytotoxicity and Crystal Structure of [Ir(ppy)<sub>2</sub>(FcCOCHCORc)]

Unexpected XPS Binding Energy Observations Further Highlighted by DFT Calculations of Ruthenocene-Containing [Ir<sup>III</sup>(ppy)<sub>2</sub>(RCOCHCORc)] Complexes: Cytotoxicity and Crystal Structure of [Ir(ppy)<sub>2</sub>(FcCOCHCORc)]

The series of iridium(III) complexes, [Ir(ppy)<sub>2</sub>(RCOCHCOR′)], with R = CH<sub>3</sub> and R′ = CH<sub>3</sub> (<b>1</b>), Rc (<b>2</b>), and Fc (<b>3</b>), as well as R = Rc and R′ = Rc (<b>4</b>) or Fc (&l...

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Bibliographic Details
Main Authors: Blenerhassitt E. Buitendach, Elizabeth Erasmus, Eleanor Fourie, Frederick P. Malan, Jeanet Conradie, J. W. (Hans) Niemantsverdriet, Jannie C. Swarts
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Molecules
Subjects:
iridium
ferrocene
ruthenocene
β-diketonato complexes
X-ray photoelectron spectroscopy
DFT calculations
Online Access:https://www.mdpi.com/1420-3049/29/22/5383
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