Photo‐Promoted Nitrogen‐Centered Radical Mediated Intermolecular Aminative Carbonylation of Tertiary Allyl Alcohols to Access β‐Amino Ketones through (Hetero)Aryl Migration

Photo‐Promoted Nitrogen‐Centered Radical Mediated Intermolecular Aminative Carbonylation of Tertiary Allyl Alcohols to Access β‐Amino Ketones through (Hetero)Aryl Migration

Abstract Carbon monoxide, as a crucial C1 synthon, has been widely used in the difunctionalization of alkenes. Additionally, nitrogen‐centered radicals (NCRs) are also effective intermediates for constructing C−N bonds. Herein, a nitrogen‐centered radical‐mediated aminative carbonylation strategy fo...

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Bibliographic Details
Main Authors: Ming Hou, Yuanrui Wang, Hefei Yang, Jiajun Zhang, Prof. Dr. Xiao‐Feng Wu
Format: Article
Language:English
Published: Wiley-VCH 2025-05-01
Series:ChemistryEurope
Subjects:
nitrogen-centered radical
photocatalysis
unactivated alkenes
carbonylation
amination
Online Access:https://doi.org/10.1002/ceur.202500001
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https://doi.org/10.1002/ceur.202500001

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