Photo‐Promoted Nitrogen‐Centered Radical Mediated Intermolecular Aminative Carbonylation of Tertiary Allyl Alcohols to Access β‐Amino Ketones through (Hetero)Aryl Migration
Abstract Carbon monoxide, as a crucial C1 synthon, has been widely used in the difunctionalization of alkenes. Additionally, nitrogen‐centered radicals (NCRs) are also effective intermediates for constructing C−N bonds. Herein, a nitrogen‐centered radical‐mediated aminative carbonylation strategy fo...
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2025-05-01
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| Series: | ChemistryEurope |
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| Online Access: | https://doi.org/10.1002/ceur.202500001 |
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| author | Ming Hou Yuanrui Wang Hefei Yang Jiajun Zhang Prof. Dr. Xiao‐Feng Wu |
| author_facet | Ming Hou Yuanrui Wang Hefei Yang Jiajun Zhang Prof. Dr. Xiao‐Feng Wu |
| author_sort | Ming Hou |
| collection | DOAJ |
| description | Abstract Carbon monoxide, as a crucial C1 synthon, has been widely used in the difunctionalization of alkenes. Additionally, nitrogen‐centered radicals (NCRs) are also effective intermediates for constructing C−N bonds. Herein, a nitrogen‐centered radical‐mediated aminative carbonylation strategy for producing β‐amino ketones from tertiary allyl alcohols has been disclosed. Good yields of β‐amino ketones with different functional groups were generated effectively under light irradiation. |
| format | Article |
| id | doaj-art-a0dac8bde9ad41f1a9e44b9a2e317ee7 |
| institution | Kabale University |
| issn | 2751-4765 |
| language | English |
| publishDate | 2025-05-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | ChemistryEurope |
| spelling | doaj-art-a0dac8bde9ad41f1a9e44b9a2e317ee72025-08-20T03:49:45ZengWiley-VCHChemistryEurope2751-47652025-05-0133n/an/a10.1002/ceur.202500001Photo‐Promoted Nitrogen‐Centered Radical Mediated Intermolecular Aminative Carbonylation of Tertiary Allyl Alcohols to Access β‐Amino Ketones through (Hetero)Aryl MigrationMing Hou0Yuanrui Wang1Hefei Yang2Jiajun Zhang3Prof. Dr. Xiao‐Feng Wu4Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics Chinese Academy of Sciences 116023 Dalian, Liaoning ChinaDalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics Chinese Academy of Sciences 116023 Dalian, Liaoning ChinaDalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics Chinese Academy of Sciences 116023 Dalian, Liaoning ChinaDalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics Chinese Academy of Sciences 116023 Dalian, Liaoning ChinaDalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics Chinese Academy of Sciences 116023 Dalian, Liaoning ChinaAbstract Carbon monoxide, as a crucial C1 synthon, has been widely used in the difunctionalization of alkenes. Additionally, nitrogen‐centered radicals (NCRs) are also effective intermediates for constructing C−N bonds. Herein, a nitrogen‐centered radical‐mediated aminative carbonylation strategy for producing β‐amino ketones from tertiary allyl alcohols has been disclosed. Good yields of β‐amino ketones with different functional groups were generated effectively under light irradiation.https://doi.org/10.1002/ceur.202500001nitrogen-centered radicalphotocatalysisunactivated alkenescarbonylationamination |
| spellingShingle | Ming Hou Yuanrui Wang Hefei Yang Jiajun Zhang Prof. Dr. Xiao‐Feng Wu Photo‐Promoted Nitrogen‐Centered Radical Mediated Intermolecular Aminative Carbonylation of Tertiary Allyl Alcohols to Access β‐Amino Ketones through (Hetero)Aryl Migration ChemistryEurope nitrogen-centered radical photocatalysis unactivated alkenes carbonylation amination |
| title | Photo‐Promoted Nitrogen‐Centered Radical Mediated Intermolecular Aminative Carbonylation of Tertiary Allyl Alcohols to Access β‐Amino Ketones through (Hetero)Aryl Migration |
| title_full | Photo‐Promoted Nitrogen‐Centered Radical Mediated Intermolecular Aminative Carbonylation of Tertiary Allyl Alcohols to Access β‐Amino Ketones through (Hetero)Aryl Migration |
| title_fullStr | Photo‐Promoted Nitrogen‐Centered Radical Mediated Intermolecular Aminative Carbonylation of Tertiary Allyl Alcohols to Access β‐Amino Ketones through (Hetero)Aryl Migration |
| title_full_unstemmed | Photo‐Promoted Nitrogen‐Centered Radical Mediated Intermolecular Aminative Carbonylation of Tertiary Allyl Alcohols to Access β‐Amino Ketones through (Hetero)Aryl Migration |
| title_short | Photo‐Promoted Nitrogen‐Centered Radical Mediated Intermolecular Aminative Carbonylation of Tertiary Allyl Alcohols to Access β‐Amino Ketones through (Hetero)Aryl Migration |
| title_sort | photo promoted nitrogen centered radical mediated intermolecular aminative carbonylation of tertiary allyl alcohols to access β amino ketones through hetero aryl migration |
| topic | nitrogen-centered radical photocatalysis unactivated alkenes carbonylation amination |
| url | https://doi.org/10.1002/ceur.202500001 |
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