Development of a high performance ethylene glycol gas sensor using cobalt doped porous ZnFe2O4 nanostructures

Abstract Porous ZnFe2O4 microspheres consisting of interwoven nanosheets doped with different concentrations of cobalt (ZC) with a diameter of approximately 1.5 μm were synthesized by a simple hydrothermal method. The synthesized samples were comprehensively characterized using XRD, FESEM, FTIR, BET...

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Main Authors: Abdulrahman Sumayli, Ruaa M. Almotawa, Jawaher Abdullah Alamoudi
Format: Article
Language:English
Published: Nature Portfolio 2025-05-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-025-00941-3
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author Abdulrahman Sumayli
Ruaa M. Almotawa
Jawaher Abdullah Alamoudi
author_facet Abdulrahman Sumayli
Ruaa M. Almotawa
Jawaher Abdullah Alamoudi
author_sort Abdulrahman Sumayli
collection DOAJ
description Abstract Porous ZnFe2O4 microspheres consisting of interwoven nanosheets doped with different concentrations of cobalt (ZC) with a diameter of approximately 1.5 μm were synthesized by a simple hydrothermal method. The synthesized samples were comprehensively characterized using XRD, FESEM, FTIR, BET, and UV-Vis analyses. The synthesized ZCs were studied to investigate the effect of doping on the gas sensing properties. Interestingly, the prepared ZCs showed enhanced gas sensing performance towards ethylene glycol, with the response value increasing from 107.5 to 119.6 for 500 ppm ethylene glycol compared to the pure ZC sample under the same conditions. The rough surface morphology that creates a high surface area and the appropriate doping effect that enhances the surface chemical oxygen accumulation by creating some new energy levels, provide a fast response (less than 3.6 s) with excellent response, allowing us to perform sensing experiments at concentrations of 20–500 ppm ethylene glycol in a short time. The ZCs-based sensors also showed significant selectivity over ethylene glycol at a low operating temperature of 210 °C through a comparison of the sensing properties with ethanol, acetone, isopropanol, and dimethylamine. The results indicate that the ZC material has special potential for ethylene glycol sensors.
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publishDate 2025-05-01
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spelling doaj-art-9fd8daa80f4a442c897e2d0cfc1c2e7e2025-08-20T03:53:58ZengNature PortfolioScientific Reports2045-23222025-05-0115111010.1038/s41598-025-00941-3Development of a high performance ethylene glycol gas sensor using cobalt doped porous ZnFe2O4 nanostructuresAbdulrahman Sumayli0Ruaa M. Almotawa1Jawaher Abdullah Alamoudi2Department of Mechanical Engineering, College of Engineering, Najran UniversityDepartment of Chemistry, College of Science, University of Hafr Al BatinDepartment of Pharmaceutical Sciences, College of Pharmacy, Princess Nourah bint Abdulrahman UniversityAbstract Porous ZnFe2O4 microspheres consisting of interwoven nanosheets doped with different concentrations of cobalt (ZC) with a diameter of approximately 1.5 μm were synthesized by a simple hydrothermal method. The synthesized samples were comprehensively characterized using XRD, FESEM, FTIR, BET, and UV-Vis analyses. The synthesized ZCs were studied to investigate the effect of doping on the gas sensing properties. Interestingly, the prepared ZCs showed enhanced gas sensing performance towards ethylene glycol, with the response value increasing from 107.5 to 119.6 for 500 ppm ethylene glycol compared to the pure ZC sample under the same conditions. The rough surface morphology that creates a high surface area and the appropriate doping effect that enhances the surface chemical oxygen accumulation by creating some new energy levels, provide a fast response (less than 3.6 s) with excellent response, allowing us to perform sensing experiments at concentrations of 20–500 ppm ethylene glycol in a short time. The ZCs-based sensors also showed significant selectivity over ethylene glycol at a low operating temperature of 210 °C through a comparison of the sensing properties with ethanol, acetone, isopropanol, and dimethylamine. The results indicate that the ZC material has special potential for ethylene glycol sensors.https://doi.org/10.1038/s41598-025-00941-3Ethylene glycol sensorPorousCobalt dopingFast responseSelectivity
spellingShingle Abdulrahman Sumayli
Ruaa M. Almotawa
Jawaher Abdullah Alamoudi
Development of a high performance ethylene glycol gas sensor using cobalt doped porous ZnFe2O4 nanostructures
Scientific Reports
Ethylene glycol sensor
Porous
Cobalt doping
Fast response
Selectivity
title Development of a high performance ethylene glycol gas sensor using cobalt doped porous ZnFe2O4 nanostructures
title_full Development of a high performance ethylene glycol gas sensor using cobalt doped porous ZnFe2O4 nanostructures
title_fullStr Development of a high performance ethylene glycol gas sensor using cobalt doped porous ZnFe2O4 nanostructures
title_full_unstemmed Development of a high performance ethylene glycol gas sensor using cobalt doped porous ZnFe2O4 nanostructures
title_short Development of a high performance ethylene glycol gas sensor using cobalt doped porous ZnFe2O4 nanostructures
title_sort development of a high performance ethylene glycol gas sensor using cobalt doped porous znfe2o4 nanostructures
topic Ethylene glycol sensor
Porous
Cobalt doping
Fast response
Selectivity
url https://doi.org/10.1038/s41598-025-00941-3
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AT ruaamalmotawa developmentofahighperformanceethyleneglycolgassensorusingcobaltdopedporousznfe2o4nanostructures
AT jawaherabdullahalamoudi developmentofahighperformanceethyleneglycolgassensorusingcobaltdopedporousznfe2o4nanostructures