Azirinyl-Substituted Nitrile Oxides: Generation and Use in the Synthesis of Isoxazole Containing Heterocyclic Hybrids

Azirinyl-Substituted Nitrile Oxides: Generation and Use in the Synthesis of Isoxazole Containing Heterocyclic Hybrids

The procedure for the generation of azirinyl-substituted nitrile oxides by the reaction of 2-(diazoacetyl)-2<i>H</i>-azirines with <i>tert</i>-butyl nitrite while preserving the azirine ring has been developed. The [3+2] cycloaddition of azirinyl-substituted nitrile oxides to...

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Bibliographic Details
Main Authors: Alexander S. Dudik, Timur O. Zanakhov, Ekaterina E. Galenko, Mikhail S. Novikov, Alexander F. Khlebnikov
Format: Article
Language:English
Published: MDPI AG 2025-07-01
Series:Molecules
Subjects:
azirines
nitrile oxides
diazo compounds
isoxazoles
pyrroles
oxazoles
Online Access:https://www.mdpi.com/1420-3049/30/13/2834
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