Application of dispersion and regression analysis to optimize the efficiency of the technological procedure of dechlorination of PCB-contaminated insulating oils
Modern experimental research theory includes plans for statistical multifactorial analysis. The advantage of this theory is that all factors are changed simultaneously so that a minimum number of experimental points distributed in the experimental hyperspace is obtained, which results in much lower...
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Electrical Engineering Institute Nikola Tesla
2024-01-01
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| Series: | Zbornik Radova: Elektrotehnički Institut "Nikola Tesla" |
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| Online Access: | https://scindeks-clanci.ceon.rs/data/pdf/0350-8528/2024/0350-85282434095M.pdf |
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| author | Marinković Savo Mihajlović Draginja Lukić Jelena Marinković Ana Naumović-Vuković Dragana |
| author_facet | Marinković Savo Mihajlović Draginja Lukić Jelena Marinković Ana Naumović-Vuković Dragana |
| author_sort | Marinković Savo |
| collection | DOAJ |
| description | Modern experimental research theory includes plans for statistical multifactorial analysis. The advantage of this theory is that all factors are changed simultaneously so that a minimum number of experimental points distributed in the experimental hyperspace is obtained, which results in much lower costs and shorter time of experimental tests. The process of decontamination of polychlorinated biphenyls (PCB) from transformer oils is based on a dechlorination reaction using a reagent mixture (KPEG) consisting of potassium hydroxide (KOH) and polyethylene glycol (PEG), whereby the PCB molecule is chemically decomposed. Using 23 orthogonal plans, the influence of the mass ratio of KPEG/oil, KOH/PEG molar ratio and temperature on the dechlorination reaction were investigated to optimize this process. The success of the reaction was evaluated by determining the efficiency of chemical degradation of PCBs (DRE) from transformer oil. The DRE values were from 81.81% to 99.81%. Using dispersion analysis, the significance and degree of interactivity of the examined factors on DRE were determined, and using regression analysis, a multilinear regression model was set up. |
| format | Article |
| id | doaj-art-8915f5a659fc444aa53d6c879fa81548 |
| institution | Kabale University |
| issn | 0350-8528 2406-1212 |
| language | English |
| publishDate | 2024-01-01 |
| publisher | Electrical Engineering Institute Nikola Tesla |
| record_format | Article |
| series | Zbornik Radova: Elektrotehnički Institut "Nikola Tesla" |
| spelling | doaj-art-8915f5a659fc444aa53d6c879fa815482025-01-08T16:53:52ZengElectrical Engineering Institute Nikola TeslaZbornik Radova: Elektrotehnički Institut "Nikola Tesla"0350-85282406-12122024-01-012024349510810.5937/zeint34-551730350-85282434095MApplication of dispersion and regression analysis to optimize the efficiency of the technological procedure of dechlorination of PCB-contaminated insulating oilsMarinković Savo0https://orcid.org/0009-0003-9487-8251Mihajlović Draginja1https://orcid.org/0000-0001-8515-855XLukić Jelena2https://orcid.org/0000-0003-3538-203XMarinković Ana3https://orcid.org/0000-0002-3206-1102Naumović-Vuković Dragana4https://orcid.org/0000-0002-8334-4452Univerzitet u Beogradu, Elektrotehnički institut Nikola Tesla, Beograd, SerbiaUniverzitet u Beogradu, Elektrotehnički institut Nikola Tesla, Beograd, SerbiaUniverzitet u Beogradu, Elektrotehnički institut Nikola Tesla, Beograd, SerbiaUniverzitet u Beogradu, Institut za nuklearne nauke Vinča, Vinča, Beograd, SerbiaUniverzitet u Beogradu, Elektrotehnički institut Nikola Tesla, Beograd, SerbiaModern experimental research theory includes plans for statistical multifactorial analysis. The advantage of this theory is that all factors are changed simultaneously so that a minimum number of experimental points distributed in the experimental hyperspace is obtained, which results in much lower costs and shorter time of experimental tests. The process of decontamination of polychlorinated biphenyls (PCB) from transformer oils is based on a dechlorination reaction using a reagent mixture (KPEG) consisting of potassium hydroxide (KOH) and polyethylene glycol (PEG), whereby the PCB molecule is chemically decomposed. Using 23 orthogonal plans, the influence of the mass ratio of KPEG/oil, KOH/PEG molar ratio and temperature on the dechlorination reaction were investigated to optimize this process. The success of the reaction was evaluated by determining the efficiency of chemical degradation of PCBs (DRE) from transformer oil. The DRE values were from 81.81% to 99.81%. Using dispersion analysis, the significance and degree of interactivity of the examined factors on DRE were determined, and using regression analysis, a multilinear regression model was set up.https://scindeks-clanci.ceon.rs/data/pdf/0350-8528/2024/0350-85282434095M.pdfmultifactorial designpcbtransformer oildechlorinationdispersion analysisregression model |
| spellingShingle | Marinković Savo Mihajlović Draginja Lukić Jelena Marinković Ana Naumović-Vuković Dragana Application of dispersion and regression analysis to optimize the efficiency of the technological procedure of dechlorination of PCB-contaminated insulating oils Zbornik Radova: Elektrotehnički Institut "Nikola Tesla" multifactorial design pcb transformer oil dechlorination dispersion analysis regression model |
| title | Application of dispersion and regression analysis to optimize the efficiency of the technological procedure of dechlorination of PCB-contaminated insulating oils |
| title_full | Application of dispersion and regression analysis to optimize the efficiency of the technological procedure of dechlorination of PCB-contaminated insulating oils |
| title_fullStr | Application of dispersion and regression analysis to optimize the efficiency of the technological procedure of dechlorination of PCB-contaminated insulating oils |
| title_full_unstemmed | Application of dispersion and regression analysis to optimize the efficiency of the technological procedure of dechlorination of PCB-contaminated insulating oils |
| title_short | Application of dispersion and regression analysis to optimize the efficiency of the technological procedure of dechlorination of PCB-contaminated insulating oils |
| title_sort | application of dispersion and regression analysis to optimize the efficiency of the technological procedure of dechlorination of pcb contaminated insulating oils |
| topic | multifactorial design pcb transformer oil dechlorination dispersion analysis regression model |
| url | https://scindeks-clanci.ceon.rs/data/pdf/0350-8528/2024/0350-85282434095M.pdf |
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