Two New 2p–3d Metal Complexes with a Nitronyl-Nitroxide Ligand Derived from <i>o</i>-Vanillin: Synthesis, Crystals Structures and Magnetic Properties

Two New 2p–3d Metal Complexes with a Nitronyl-Nitroxide Ligand Derived from <i>o</i>-Vanillin: Synthesis, Crystals Structures and Magnetic Properties

Two new 2p–3d complexes, (Et<sub>3</sub>NH)[ML(hfac)<sub>2</sub>], have been obtained using the nitronyl-nitroxide radical (HL) derived from 2-hydroxy-3-methoxy-5-nitrobenzaldehyde (M = Mn <b>1</b>; Co <b>2</b>). The two compounds are isomorphous and t...

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Bibliographic Details
Main Authors: Cristian Andrei Spinu, Daniel O. T. A. Martins, Teodora Mocanu, Mihaela Hillebrand, Jean-Pascal Sutter, Floriana Tuna, Marius Andruh
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Magnetochemistry
Subjects:
manganese(II) complexes
cobalt(II) complexes
nitronyl-nitroxide ligands
EPR spectra
cryomagnetic measurements
Online Access:https://www.mdpi.com/2312-7481/10/11/86
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