Pyridinium-based ionic liquids as anti-wear additives for calcium sulfonate greases

The present study showed the usage of ionic liquids as anti-wear additives for greases. New pyridinium-based ionic liquids bearing long alkyl chains were prepared and evaluated as wear-reducing additives in calcium sulfonate greases. The physical properties of the synthetic ionic liquids were identi...

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Main Authors: Nikita Semenov, Nikolay Pugachev, Anna Peskovets
Format: Article
Language:English
Published: Balkan Scientific Centre 2024-12-01
Series:Tribology and Materials
Subjects:
Online Access:https://www.tribomat.net/archive/2024/2024-04/TM-2024-04-03.pdf
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author Nikita Semenov
Nikolay Pugachev
Anna Peskovets
author_facet Nikita Semenov
Nikolay Pugachev
Anna Peskovets
author_sort Nikita Semenov
collection DOAJ
description The present study showed the usage of ionic liquids as anti-wear additives for greases. New pyridinium-based ionic liquids bearing long alkyl chains were prepared and evaluated as wear-reducing additives in calcium sulfonate greases. The physical properties of the synthetic ionic liquids were identified. The obtained liquids were then added to greases at a concentration of 2 wt. %. The tribological performance of the greases was measured by using a standard benchtop test ASTM D2266. The results obtained allow us to conclude that the introduction of ionic liquids into polyalkylene glycol (PAG)-based calcium sulfonate grease has a positive effect on anti-wear properties since the wear decreases by several orders of magnitude. The interoperability of the synthetic ionic liquids with the calcium sulfonate greases and its potential influence upon solubility and tribological performance are tentatively proposed to be a result of the molecular structure.
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institution Kabale University
issn 2812-9717
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publishDate 2024-12-01
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series Tribology and Materials
spelling doaj-art-7e9025bc8c294647bafb4286546342902025-01-06T12:46:44ZengBalkan Scientific CentreTribology and Materials2812-97172024-12-013417217710.46793/tribomat.2024.017Pyridinium-based ionic liquids as anti-wear additives for calcium sulfonate greasesNikita Semenov0https://orcid.org/0009-0003-7078-4779Nikolay Pugachev1https://orcid.org/0009-0003-9882-1818Anna Peskovets2https://orcid.org/0009-0005-2191-392XNational University of Oil and Gas "Gubkin University", Moscow, RussiaNational University of Oil and Gas "Gubkin University", Moscow, RussiaNational University of Oil and Gas "Gubkin University", Moscow, RussiaThe present study showed the usage of ionic liquids as anti-wear additives for greases. New pyridinium-based ionic liquids bearing long alkyl chains were prepared and evaluated as wear-reducing additives in calcium sulfonate greases. The physical properties of the synthetic ionic liquids were identified. The obtained liquids were then added to greases at a concentration of 2 wt. %. The tribological performance of the greases was measured by using a standard benchtop test ASTM D2266. The results obtained allow us to conclude that the introduction of ionic liquids into polyalkylene glycol (PAG)-based calcium sulfonate grease has a positive effect on anti-wear properties since the wear decreases by several orders of magnitude. The interoperability of the synthetic ionic liquids with the calcium sulfonate greases and its potential influence upon solubility and tribological performance are tentatively proposed to be a result of the molecular structure.https://www.tribomat.net/archive/2024/2024-04/TM-2024-04-03.pdfionic liquidsanti-wear additivessulfonate grease
spellingShingle Nikita Semenov
Nikolay Pugachev
Anna Peskovets
Pyridinium-based ionic liquids as anti-wear additives for calcium sulfonate greases
Tribology and Materials
ionic liquids
anti-wear additives
sulfonate grease
title Pyridinium-based ionic liquids as anti-wear additives for calcium sulfonate greases
title_full Pyridinium-based ionic liquids as anti-wear additives for calcium sulfonate greases
title_fullStr Pyridinium-based ionic liquids as anti-wear additives for calcium sulfonate greases
title_full_unstemmed Pyridinium-based ionic liquids as anti-wear additives for calcium sulfonate greases
title_short Pyridinium-based ionic liquids as anti-wear additives for calcium sulfonate greases
title_sort pyridinium based ionic liquids as anti wear additives for calcium sulfonate greases
topic ionic liquids
anti-wear additives
sulfonate grease
url https://www.tribomat.net/archive/2024/2024-04/TM-2024-04-03.pdf
work_keys_str_mv AT nikitasemenov pyridiniumbasedionicliquidsasantiwearadditivesforcalciumsulfonategreases
AT nikolaypugachev pyridiniumbasedionicliquidsasantiwearadditivesforcalciumsulfonategreases
AT annapeskovets pyridiniumbasedionicliquidsasantiwearadditivesforcalciumsulfonategreases