Synthesis, crystal structure and properties of catena-poly[[bis(4-methylpyridine-κN)cobalt(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N], which shows a rare coordination geometry

Synthesis, crystal structure and properties of catena-poly[[bis(4-methylpyridine-κN)cobalt(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N], which shows a rare coordination geometry

Reaction of Co(NCS)2 with 4-methylpyridine in water leads to the formation of single crystals of the title compound, [Co(NCS)2(C6H7N)2]n. The asymmetric unit consists of two crystallographically independent thiocyanate anions and two crystallographically independent 4-methylpyridine coligands in gen...

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Bibliographic Details
Main Authors: Christian Näther, Jan Boeckmann
Format: Article
Language:English
Published: International Union of Crystallography 2025-01-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
synthesis
crystal structure
coordination polymer
chain structure
spectroscopic properties
cobalt thiocyanate
4-methylpyridine
Online Access:https://journals.iucr.org/paper?S2056989024012003
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