Catalytic auto-oxidation of o-hydroxyphenylthiourea by Iridium(III): A photometric sensing platform for Iridium

o-Hydroxyphenylthiourea (HPTU) undergoes oxidative dimerization to form a yellow-colored disulfide in the presence of Iridium(III), a process significantly enhanced by the activator 1,10-phenanthroline. This catalytic oxidation was monitored spectrophotometrically at 416 ​nm under ambient conditions...

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Bibliographic Details
Main Authors: A. Sunil, Ashish Deep Chettri, S. Jagadeeswara Rao
Format: Article
Language:English
Published: Elsevier 2024-12-01
Series:Chemistry of Inorganic Materials
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Online Access:http://www.sciencedirect.com/science/article/pii/S2949746924000491
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