Harnessing tethered nitreniums for diastereoselective amino-sulfonoxylation of alkenes

Harnessing tethered nitreniums for diastereoselective amino-sulfonoxylation of alkenes

We present the first examples of alkene amino-sulfonoxylation reactions that leverage the unique reactivity of carbamate tethered N-alkoxy nitrenium ions. In almost all cases examined, the reactions deliver product with exquisite regioselectivity and diastereoselectivity. The protocols followed are...

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Bibliographic Details
Main Authors:	Shyam Sathyamoorthi, Appasaheb K. Nirpal, Dnyaneshwar A. Gorve, Steven P. Kelley
Format:	Article
Language:	English
Published:	Beilstein-Institut 2025-05-01
Series:	Beilstein Journal of Organic Chemistry
Subjects:	alkene amino-sulfonoxylation metal-free tethered nitrenium
Online Access:	https://doi.org/10.3762/bjoc.21.78
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