Harnessing tethered nitreniums for diastereoselective amino-sulfonoxylation of alkenes

We present the first examples of alkene amino-sulfonoxylation reactions that leverage the unique reactivity of carbamate tethered N-alkoxy nitrenium ions. In almost all cases examined, the reactions deliver product with exquisite regioselectivity and diastereoselectivity. The protocols followed are...

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Bibliographic Details
Main Authors: Shyam Sathyamoorthi, Appasaheb K. Nirpal, Dnyaneshwar A. Gorve, Steven P. Kelley
Format: Article
Language:English
Published: Beilstein-Institut 2025-05-01
Series:Beilstein Journal of Organic Chemistry
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Online Access:https://doi.org/10.3762/bjoc.21.78
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