Efficient CO<sub>2</sub> Electrocarboxylation Using Dye-Sensitized Photovoltaics
This paper presents the solar-driven electrocarboxylation of 2-bromopyridine (2-BP) with CO<sub>2</sub> into high-value-added chemicals 2-picolinic acid (2-PA) using dye-sensitized photovoltaics under simulated sunlight. Using three series-connected photovoltaic modules and an Ag electro...
Saved in:
| Main Authors: | , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2024-12-01
|
| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/30/1/40 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1841549145450479616 |
|---|---|
| author | Yingtian Zhang Huaiyan Ren Huawei Zhou Peipei Luo Qi Wan Xianxi Zhang Bo Wang Baoli Chen Bo Zhang |
| author_facet | Yingtian Zhang Huaiyan Ren Huawei Zhou Peipei Luo Qi Wan Xianxi Zhang Bo Wang Baoli Chen Bo Zhang |
| author_sort | Yingtian Zhang |
| collection | DOAJ |
| description | This paper presents the solar-driven electrocarboxylation of 2-bromopyridine (2-BP) with CO<sub>2</sub> into high-value-added chemicals 2-picolinic acid (2-PA) using dye-sensitized photovoltaics under simulated sunlight. Using three series-connected photovoltaic modules and an Ag electrode with excellent catalytic performance, a Faraday efficiency (<i>FE</i>) of 33.3% is obtained for 2-PA under mild conditions. The experimental results show that photovoltaics-driven systems for electrocarboxylation conversion of CO<sub>2</sub> with heterocyclic halide to afford value-added heterocyclic carboxylic acid are feasible and effective. |
| format | Article |
| id | doaj-art-69961863799c455881bc576c53a8c414 |
| institution | Kabale University |
| issn | 1420-3049 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj-art-69961863799c455881bc576c53a8c4142025-01-10T13:18:41ZengMDPI AGMolecules1420-30492024-12-013014010.3390/molecules30010040Efficient CO<sub>2</sub> Electrocarboxylation Using Dye-Sensitized PhotovoltaicsYingtian Zhang0Huaiyan Ren1Huawei Zhou2Peipei Luo3Qi Wan4Xianxi Zhang5Bo Wang6Baoli Chen7Bo Zhang8School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, ChinaSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, ChinaSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, ChinaSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, ChinaSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, ChinaSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, ChinaSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, ChinaSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, ChinaSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, ChinaThis paper presents the solar-driven electrocarboxylation of 2-bromopyridine (2-BP) with CO<sub>2</sub> into high-value-added chemicals 2-picolinic acid (2-PA) using dye-sensitized photovoltaics under simulated sunlight. Using three series-connected photovoltaic modules and an Ag electrode with excellent catalytic performance, a Faraday efficiency (<i>FE</i>) of 33.3% is obtained for 2-PA under mild conditions. The experimental results show that photovoltaics-driven systems for electrocarboxylation conversion of CO<sub>2</sub> with heterocyclic halide to afford value-added heterocyclic carboxylic acid are feasible and effective.https://www.mdpi.com/1420-3049/30/1/40electrochemical carboxylationelectrocarboxylationCO<sub>2</sub> fixationCO<sub>2</sub> electrocatalytic carboxylationelectrosynthesisdye-sensitized solar cells |
| spellingShingle | Yingtian Zhang Huaiyan Ren Huawei Zhou Peipei Luo Qi Wan Xianxi Zhang Bo Wang Baoli Chen Bo Zhang Efficient CO<sub>2</sub> Electrocarboxylation Using Dye-Sensitized Photovoltaics Molecules electrochemical carboxylation electrocarboxylation CO<sub>2</sub> fixation CO<sub>2</sub> electrocatalytic carboxylation electrosynthesis dye-sensitized solar cells |
| title | Efficient CO<sub>2</sub> Electrocarboxylation Using Dye-Sensitized Photovoltaics |
| title_full | Efficient CO<sub>2</sub> Electrocarboxylation Using Dye-Sensitized Photovoltaics |
| title_fullStr | Efficient CO<sub>2</sub> Electrocarboxylation Using Dye-Sensitized Photovoltaics |
| title_full_unstemmed | Efficient CO<sub>2</sub> Electrocarboxylation Using Dye-Sensitized Photovoltaics |
| title_short | Efficient CO<sub>2</sub> Electrocarboxylation Using Dye-Sensitized Photovoltaics |
| title_sort | efficient co sub 2 sub electrocarboxylation using dye sensitized photovoltaics |
| topic | electrochemical carboxylation electrocarboxylation CO<sub>2</sub> fixation CO<sub>2</sub> electrocatalytic carboxylation electrosynthesis dye-sensitized solar cells |
| url | https://www.mdpi.com/1420-3049/30/1/40 |
| work_keys_str_mv | AT yingtianzhang efficientcosub2subelectrocarboxylationusingdyesensitizedphotovoltaics AT huaiyanren efficientcosub2subelectrocarboxylationusingdyesensitizedphotovoltaics AT huaweizhou efficientcosub2subelectrocarboxylationusingdyesensitizedphotovoltaics AT peipeiluo efficientcosub2subelectrocarboxylationusingdyesensitizedphotovoltaics AT qiwan efficientcosub2subelectrocarboxylationusingdyesensitizedphotovoltaics AT xianxizhang efficientcosub2subelectrocarboxylationusingdyesensitizedphotovoltaics AT bowang efficientcosub2subelectrocarboxylationusingdyesensitizedphotovoltaics AT baolichen efficientcosub2subelectrocarboxylationusingdyesensitizedphotovoltaics AT bozhang efficientcosub2subelectrocarboxylationusingdyesensitizedphotovoltaics |