Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SO
In this study, sorption of gaseous SO 2 on nitrogen-modified titanium dioxide (TiO 2 /N) materials was investigated. The TiO 2 /N materials were prepared by thermal modification of commercial TiO 2 in gaseous ammonia flow. First, TiO 2 was calcined at 100–700 °C (Δt = 200 °C). The obtained samples w...
Saved in:
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
SAGE Publishing
2014-05-01
|
Series: | Adsorption Science & Technology |
Online Access: | https://doi.org/10.1260/0263-6174.32.5.403 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
_version_ | 1841564538534625280 |
---|---|
author | Agnieszka Wanag Ewelina Kusiak-Nejman Joanna Kapica Łukasz Kowalczyk Antoni W. Morawski |
author_facet | Agnieszka Wanag Ewelina Kusiak-Nejman Joanna Kapica Łukasz Kowalczyk Antoni W. Morawski |
author_sort | Agnieszka Wanag |
collection | DOAJ |
description | In this study, sorption of gaseous SO 2 on nitrogen-modified titanium dioxide (TiO 2 /N) materials was investigated. The TiO 2 /N materials were prepared by thermal modification of commercial TiO 2 in gaseous ammonia flow. First, TiO 2 was calcined at 100–700 °C (Δt = 200 °C). The obtained samples were then rinsed with water to remove the residual ammonium groups adsorbed on the TiO 2 surface. The influence of modification temperature, BET surface area, pore volume and nitrogen content on the efficiency of SO 2 sorption on TiO 2 surface was discussed. The best result was obtained for nitrogen-modified material that is heat treated at 100 °C. The total sorption capacity calculated for this sample was 20.96 mg SO 2 /1 g TiO 2 . It was shown that TiO 2 modified with nitrogen at low temperature can be a very effective sorbent in capturing SO 2 particles. |
format | Article |
id | doaj-art-616e75f95d3741798502f7abb2d79606 |
institution | Kabale University |
issn | 0263-6174 2048-4038 |
language | English |
publishDate | 2014-05-01 |
publisher | SAGE Publishing |
record_format | Article |
series | Adsorption Science & Technology |
spelling | doaj-art-616e75f95d3741798502f7abb2d796062025-01-02T22:37:41ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382014-05-013210.1260/0263-6174.32.5.403Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SOAgnieszka WanagEwelina Kusiak-NejmanJoanna KapicaŁukasz KowalczykAntoni W. MorawskiIn this study, sorption of gaseous SO 2 on nitrogen-modified titanium dioxide (TiO 2 /N) materials was investigated. The TiO 2 /N materials were prepared by thermal modification of commercial TiO 2 in gaseous ammonia flow. First, TiO 2 was calcined at 100–700 °C (Δt = 200 °C). The obtained samples were then rinsed with water to remove the residual ammonium groups adsorbed on the TiO 2 surface. The influence of modification temperature, BET surface area, pore volume and nitrogen content on the efficiency of SO 2 sorption on TiO 2 surface was discussed. The best result was obtained for nitrogen-modified material that is heat treated at 100 °C. The total sorption capacity calculated for this sample was 20.96 mg SO 2 /1 g TiO 2 . It was shown that TiO 2 modified with nitrogen at low temperature can be a very effective sorbent in capturing SO 2 particles.https://doi.org/10.1260/0263-6174.32.5.403 |
spellingShingle | Agnieszka Wanag Ewelina Kusiak-Nejman Joanna Kapica Łukasz Kowalczyk Antoni W. Morawski Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SO Adsorption Science & Technology |
title | Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SO |
title_full | Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SO |
title_fullStr | Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SO |
title_full_unstemmed | Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SO |
title_short | Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SO |
title_sort | nitrogen modified titanium dioxide as an adsorbent for gaseous so |
url | https://doi.org/10.1260/0263-6174.32.5.403 |
work_keys_str_mv | AT agnieszkawanag nitrogenmodifiedtitaniumdioxideasanadsorbentforgaseousso AT ewelinakusiaknejman nitrogenmodifiedtitaniumdioxideasanadsorbentforgaseousso AT joannakapica nitrogenmodifiedtitaniumdioxideasanadsorbentforgaseousso AT łukaszkowalczyk nitrogenmodifiedtitaniumdioxideasanadsorbentforgaseousso AT antoniwmorawski nitrogenmodifiedtitaniumdioxideasanadsorbentforgaseousso |