Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SO

In this study, sorption of gaseous SO 2 on nitrogen-modified titanium dioxide (TiO 2 /N) materials was investigated. The TiO 2 /N materials were prepared by thermal modification of commercial TiO 2 in gaseous ammonia flow. First, TiO 2 was calcined at 100–700 °C (Δt = 200 °C). The obtained samples w...

Full description

Saved in:
Bibliographic Details
Main Authors: Agnieszka Wanag, Ewelina Kusiak-Nejman, Joanna Kapica, Łukasz Kowalczyk, Antoni W. Morawski
Format: Article
Language:English
Published: SAGE Publishing 2014-05-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263-6174.32.5.403
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1841564538534625280
author Agnieszka Wanag
Ewelina Kusiak-Nejman
Joanna Kapica
Łukasz Kowalczyk
Antoni W. Morawski
author_facet Agnieszka Wanag
Ewelina Kusiak-Nejman
Joanna Kapica
Łukasz Kowalczyk
Antoni W. Morawski
author_sort Agnieszka Wanag
collection DOAJ
description In this study, sorption of gaseous SO 2 on nitrogen-modified titanium dioxide (TiO 2 /N) materials was investigated. The TiO 2 /N materials were prepared by thermal modification of commercial TiO 2 in gaseous ammonia flow. First, TiO 2 was calcined at 100–700 °C (Δt = 200 °C). The obtained samples were then rinsed with water to remove the residual ammonium groups adsorbed on the TiO 2 surface. The influence of modification temperature, BET surface area, pore volume and nitrogen content on the efficiency of SO 2 sorption on TiO 2 surface was discussed. The best result was obtained for nitrogen-modified material that is heat treated at 100 °C. The total sorption capacity calculated for this sample was 20.96 mg SO 2 /1 g TiO 2 . It was shown that TiO 2 modified with nitrogen at low temperature can be a very effective sorbent in capturing SO 2 particles.
format Article
id doaj-art-616e75f95d3741798502f7abb2d79606
institution Kabale University
issn 0263-6174
2048-4038
language English
publishDate 2014-05-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-616e75f95d3741798502f7abb2d796062025-01-02T22:37:41ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382014-05-013210.1260/0263-6174.32.5.403Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SOAgnieszka WanagEwelina Kusiak-NejmanJoanna KapicaŁukasz KowalczykAntoni W. MorawskiIn this study, sorption of gaseous SO 2 on nitrogen-modified titanium dioxide (TiO 2 /N) materials was investigated. The TiO 2 /N materials were prepared by thermal modification of commercial TiO 2 in gaseous ammonia flow. First, TiO 2 was calcined at 100–700 °C (Δt = 200 °C). The obtained samples were then rinsed with water to remove the residual ammonium groups adsorbed on the TiO 2 surface. The influence of modification temperature, BET surface area, pore volume and nitrogen content on the efficiency of SO 2 sorption on TiO 2 surface was discussed. The best result was obtained for nitrogen-modified material that is heat treated at 100 °C. The total sorption capacity calculated for this sample was 20.96 mg SO 2 /1 g TiO 2 . It was shown that TiO 2 modified with nitrogen at low temperature can be a very effective sorbent in capturing SO 2 particles.https://doi.org/10.1260/0263-6174.32.5.403
spellingShingle Agnieszka Wanag
Ewelina Kusiak-Nejman
Joanna Kapica
Łukasz Kowalczyk
Antoni W. Morawski
Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SO
Adsorption Science & Technology
title Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SO
title_full Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SO
title_fullStr Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SO
title_full_unstemmed Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SO
title_short Nitrogen-Modified Titanium Dioxide as an Adsorbent for Gaseous SO
title_sort nitrogen modified titanium dioxide as an adsorbent for gaseous so
url https://doi.org/10.1260/0263-6174.32.5.403
work_keys_str_mv AT agnieszkawanag nitrogenmodifiedtitaniumdioxideasanadsorbentforgaseousso
AT ewelinakusiaknejman nitrogenmodifiedtitaniumdioxideasanadsorbentforgaseousso
AT joannakapica nitrogenmodifiedtitaniumdioxideasanadsorbentforgaseousso
AT łukaszkowalczyk nitrogenmodifiedtitaniumdioxideasanadsorbentforgaseousso
AT antoniwmorawski nitrogenmodifiedtitaniumdioxideasanadsorbentforgaseousso