Crystal structures of two polymorphs for fac-bromidotricarbonyl[4-(4-methoxyphenyl)-2-(pyridin-2-yl)thiazole-κ2N,N′]rhenium(I)

Crystal structures of two polymorphs for fac-bromidotricarbonyl[4-(4-methoxyphenyl)-2-(pyridin-2-yl)thiazole-κ2N,N′]rhenium(I)

Crystallization of the title compound, fac-[ReBr(ppt-OMe)(CO)3] (ppt-OMe = C15H12N2OS), from CH2Cl2/n-pentane (1:5 v/v) at room temperature gave two polymorphs, which crystallize in monoclinic (P21/c; α form) and orthorhombic (Pna21; β form) space groups. The ReI complex molecules in either polymorp...

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Bibliographic Details
Main Authors: Yuki Matsuda, Ryota Nakamura, Yoshiki Ozawa, Masaaki Abe
Format: Article
Language:English
Published: International Union of Crystallography 2024-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
polymorph
rhenium(i) complex
chelating ligand
hydrogen bond
photoluminescence
Online Access:https://journals.iucr.org/paper?S2056989024010727
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