Sustainable synthesis of silver nanoparticles using Cynometra ramiflora leaf extract for methyl orange degradation

Abstract This study presents an eco-friendly method to synthesize silver nanoparticles (AgNPs) utilizing the leaf extract of Cynometra ramiflora as a bio-reducing agent. A distinct 431 nm surface plasmon resonance signal confirmed the formation of AgNPs. SEM images portrayed uniformly distributed sp...

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Bibliographic Details
Main Authors: Raja Selvaraj, Stuthi A. Shetty, Gokulakrishnan Murugesan, Thivaharan Varadavenkatesan, Ramesh Vinayagam
Format: Article
Language:English
Published: Springer 2025-06-01
Series:Discover Applied Sciences
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Online Access:https://doi.org/10.1007/s42452-025-07276-8
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Summary:Abstract This study presents an eco-friendly method to synthesize silver nanoparticles (AgNPs) utilizing the leaf extract of Cynometra ramiflora as a bio-reducing agent. A distinct 431 nm surface plasmon resonance signal confirmed the formation of AgNPs. SEM images portrayed uniformly distributed spherical nanoparticles with smooth surfaces. EDX analysis showed a prominent peak at 3 keV, confirming elemental silver. TEM analysis indicated that most AgNPs were 10–25 nm in size, with a mean size of 18.84 nm. XRD confirmed the face-centered cubic nature of the AgNPs. The d-spacing for the (111) plane was found to be 0.2287 nm, in agreement with standard reference values. FTIR analysis demonstrated signals at 3301, 1637, and 843 cm−1, indicating the engagement of functional moieties in reducing and capping the AgNPs. The synthesized AgNPs had a high zeta potential (− 18.2 mV), revealing good stability. The AgNPs demonstrated excellent catalytic potential in the presence of NaBH4, degrading approximately 95% of methyl orange dye within 15 min, following a pseudo-first-order kinetic model with a kinetic constant of 0.186 min−1.
ISSN:3004-9261