Exploring chemical properties of essential oils from citrus peels using green solvent

The research explored the chemical characteristics of essential oils (EOs) extracted from the peels of four citrus fruits grown in northeastern Peru (lime, sweet lemon, mandarin and orange). The essential oils were extracted by hydrodistillation using a green solvent, and subsequently, their physico...

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Main Authors: Katheryn L. Vasquez-Gomez, Diner Mori-Mestanza, Aline C. Caetano, Guillermo Idrogo-Vasquez, Carlos Culqui-Arce, Erick A. Auquiñivin-Silva, Efraín M. Castro-Alayo, Rosita Cruz-Lacerna, Harvey A. Perez-Ramos, César R. Balcázar-Zumaeta, Llisela Torrejón-Valqui, Cindy Yoplac-Collantes, Ives Yoplac, Segundo G. Chavez
Format: Article
Language:English
Published: Elsevier 2024-11-01
Series:Heliyon
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Online Access:http://www.sciencedirect.com/science/article/pii/S2405844024161191
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author Katheryn L. Vasquez-Gomez
Diner Mori-Mestanza
Aline C. Caetano
Guillermo Idrogo-Vasquez
Carlos Culqui-Arce
Erick A. Auquiñivin-Silva
Efraín M. Castro-Alayo
Rosita Cruz-Lacerna
Harvey A. Perez-Ramos
César R. Balcázar-Zumaeta
Llisela Torrejón-Valqui
Cindy Yoplac-Collantes
Ives Yoplac
Segundo G. Chavez
author_facet Katheryn L. Vasquez-Gomez
Diner Mori-Mestanza
Aline C. Caetano
Guillermo Idrogo-Vasquez
Carlos Culqui-Arce
Erick A. Auquiñivin-Silva
Efraín M. Castro-Alayo
Rosita Cruz-Lacerna
Harvey A. Perez-Ramos
César R. Balcázar-Zumaeta
Llisela Torrejón-Valqui
Cindy Yoplac-Collantes
Ives Yoplac
Segundo G. Chavez
author_sort Katheryn L. Vasquez-Gomez
collection DOAJ
description The research explored the chemical characteristics of essential oils (EOs) extracted from the peels of four citrus fruits grown in northeastern Peru (lime, sweet lemon, mandarin and orange). The essential oils were extracted by hydrodistillation using a green solvent, and subsequently, their physicochemical profile, bioactive, heat capacity, and RAMAN mapping were determined; in addition, the volatile composition was determined by gas chromatography (GC-MS), and the main phenols by liquid chromatography (UHPLC). The results evidenced that sweet lemon and mandarin essential oils had higher antioxidant activity (1592.38 and 1216.13 μmol TE/g) and total phenolic content (680.78 and 420.28 mg GAE/g). In contrast, sweet lemon peel essential oil had the highest total flavonoid content (23.18 mg QE/g). D-limonene was the most abundant aromatic compound in orange (>67 %), mandarin (>70 %), and sweet lemon (>72 %) EOs; however, in the lime, it was the lowest (37 %). The most abundant component was the cyclobutane, 1,2-bis(1-methylethylethylenyl)-, trans- (32 %).
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spelling doaj-art-4f73333e602b4671a8943dd15f3e8b512024-11-15T06:14:23ZengElsevierHeliyon2405-84402024-11-011021e40088Exploring chemical properties of essential oils from citrus peels using green solventKatheryn L. Vasquez-Gomez0Diner Mori-Mestanza1Aline C. Caetano2Guillermo Idrogo-Vasquez3Carlos Culqui-Arce4Erick A. Auquiñivin-Silva5Efraín M. Castro-Alayo6Rosita Cruz-Lacerna7Harvey A. Perez-Ramos8César R. Balcázar-Zumaeta9Llisela Torrejón-Valqui10Cindy Yoplac-Collantes11Ives Yoplac12Segundo G. Chavez13Instituto de Investigación, Innovación y Desarrollo para el Sector Agrario y Agroindustrial (IIDAA), Facultad de Ingeniería y Ciencias Agrarias, Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas, Chachapoyas, 01001, PeruInstituto de Investigación, Innovación y Desarrollo para el Sector Agrario y Agroindustrial (IIDAA), Facultad de Ingeniería y Ciencias Agrarias, Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas, Chachapoyas, 01001, PeruInstituto de Investigación para el Desarrollo Sustentable de Ceja de Selva (INDES-CES), Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas, Chachapoyas, 01001, PeruInstituto de Investigación, Innovación y Desarrollo para el Sector Agrario y Agroindustrial (IIDAA), Facultad de Ingeniería y Ciencias Agrarias, Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas, Chachapoyas, 01001, PeruInstituto de Investigación, Innovación y Desarrollo para el Sector Agrario y Agroindustrial (IIDAA), Facultad de Ingeniería y Ciencias Agrarias, Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas, Chachapoyas, 01001, PeruInstituto de Investigación, Innovación y Desarrollo para el Sector Agrario y Agroindustrial (IIDAA), Facultad de Ingeniería y Ciencias Agrarias, Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas, Chachapoyas, 01001, PeruInstituto de Investigación, Innovación y Desarrollo para el Sector Agrario y Agroindustrial (IIDAA), Facultad de Ingeniería y Ciencias Agrarias, Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas, Chachapoyas, 01001, PeruInstituto de Investigación, Innovación y Desarrollo para el Sector Agrario y Agroindustrial (IIDAA), Facultad de Ingeniería y Ciencias Agrarias, Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas, Chachapoyas, 01001, PeruInstituto de Investigación, Innovación y Desarrollo para el Sector Agrario y Agroindustrial (IIDAA), Facultad de Ingeniería y Ciencias Agrarias, Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas, Chachapoyas, 01001, PeruInstituto de Investigación, Innovación y Desarrollo para el Sector Agrario y Agroindustrial (IIDAA), Facultad de Ingeniería y Ciencias Agrarias, Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas, Chachapoyas, 01001, PeruInstituto de Investigación, Innovación y Desarrollo para el Sector Agrario y Agroindustrial (IIDAA), Facultad de Ingeniería y Ciencias Agrarias, Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas, Chachapoyas, 01001, PeruInstituto de Investigación, Innovación y Desarrollo para el Sector Agrario y Agroindustrial (IIDAA), Facultad de Ingeniería y Ciencias Agrarias, Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas, Chachapoyas, 01001, PeruLaboratorio de Nutrición Animal y Bromatología de alimentos, Facultad de Ingeniería Zootecnista, Agronegocios y Biotecnología, Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas, Chachapoyas, 01001, PeruInstituto de Investigación, Innovación y Desarrollo para el Sector Agrario y Agroindustrial (IIDAA), Facultad de Ingeniería y Ciencias Agrarias, Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas, Chachapoyas, 01001, Peru; Corresponding author. Instituto de Investigación, Innovación y Desarrollo para el Sector Agrario y Agroindustrial de la Región Amazonas (IIDAA), Facultad de Ingeniería y Ciencias Agrarias, Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas. Calle Higos Urco 342-350-356, Chachapoyas, 01001, Peru.The research explored the chemical characteristics of essential oils (EOs) extracted from the peels of four citrus fruits grown in northeastern Peru (lime, sweet lemon, mandarin and orange). The essential oils were extracted by hydrodistillation using a green solvent, and subsequently, their physicochemical profile, bioactive, heat capacity, and RAMAN mapping were determined; in addition, the volatile composition was determined by gas chromatography (GC-MS), and the main phenols by liquid chromatography (UHPLC). The results evidenced that sweet lemon and mandarin essential oils had higher antioxidant activity (1592.38 and 1216.13 μmol TE/g) and total phenolic content (680.78 and 420.28 mg GAE/g). In contrast, sweet lemon peel essential oil had the highest total flavonoid content (23.18 mg QE/g). D-limonene was the most abundant aromatic compound in orange (>67 %), mandarin (>70 %), and sweet lemon (>72 %) EOs; however, in the lime, it was the lowest (37 %). The most abundant component was the cyclobutane, 1,2-bis(1-methylethylethylenyl)-, trans- (32 %).http://www.sciencedirect.com/science/article/pii/S2405844024161191CromatographySpectroscopyVolatile compoundsD-limoneneRaman
spellingShingle Katheryn L. Vasquez-Gomez
Diner Mori-Mestanza
Aline C. Caetano
Guillermo Idrogo-Vasquez
Carlos Culqui-Arce
Erick A. Auquiñivin-Silva
Efraín M. Castro-Alayo
Rosita Cruz-Lacerna
Harvey A. Perez-Ramos
César R. Balcázar-Zumaeta
Llisela Torrejón-Valqui
Cindy Yoplac-Collantes
Ives Yoplac
Segundo G. Chavez
Exploring chemical properties of essential oils from citrus peels using green solvent
Heliyon
Cromatography
Spectroscopy
Volatile compounds
D-limonene
Raman
title Exploring chemical properties of essential oils from citrus peels using green solvent
title_full Exploring chemical properties of essential oils from citrus peels using green solvent
title_fullStr Exploring chemical properties of essential oils from citrus peels using green solvent
title_full_unstemmed Exploring chemical properties of essential oils from citrus peels using green solvent
title_short Exploring chemical properties of essential oils from citrus peels using green solvent
title_sort exploring chemical properties of essential oils from citrus peels using green solvent
topic Cromatography
Spectroscopy
Volatile compounds
D-limonene
Raman
url http://www.sciencedirect.com/science/article/pii/S2405844024161191
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