Structural analysis of the stable form of fibroblast growth factor 2 – FGF2-STAB

Fibroblast growth factor 2 (FGF2) is a signaling protein that plays a significant role in tissue development and repair. FGF2 binds to fibroblast growth factor receptors (FGFRs) alongside its co-factor heparin, which protects FGF2 from degradation. The binding between FGF2 and FGFRs induces intracel...

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Main Authors: Gabin de La Bourdonnaye, Martin Marek, Tereza Ghazalova, Jiri Damborsky, Petr Pachl, Jiri Brynda, Veronika Stepankova, Radka Chaloupkova
Format: Article
Language:English
Published: Elsevier 2024-12-01
Series:Journal of Structural Biology: X
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Online Access:http://www.sciencedirect.com/science/article/pii/S2590152424000175
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author Gabin de La Bourdonnaye
Martin Marek
Tereza Ghazalova
Jiri Damborsky
Petr Pachl
Jiri Brynda
Veronika Stepankova
Radka Chaloupkova
author_facet Gabin de La Bourdonnaye
Martin Marek
Tereza Ghazalova
Jiri Damborsky
Petr Pachl
Jiri Brynda
Veronika Stepankova
Radka Chaloupkova
author_sort Gabin de La Bourdonnaye
collection DOAJ
description Fibroblast growth factor 2 (FGF2) is a signaling protein that plays a significant role in tissue development and repair. FGF2 binds to fibroblast growth factor receptors (FGFRs) alongside its co-factor heparin, which protects FGF2 from degradation. The binding between FGF2 and FGFRs induces intracellular signaling pathways such as RAS-MAPK, PI3K-AKT, and STAT. FGF2 has strong potential for application in cell culturing, wound healing, and cosmetics but the potential is severely limited by its low protein stability. The thermostable variant FGF2-STAB was constructed by computer-assisted protein engineering to overcome the natural limitation of FGF2. Previously reported characterization of FGF2-STAB revealed an enhanced ability to induce MAP/ERK signaling while having a lower dependence on heparin when compared with FGF2-wt. Here we report the crystal structure of FGF2-STAB solved at 1.3 Å resolution. Protein stabilization is achieved by newly formed hydrophobic interactions, polar contacts, and one additional hydrogen bond. The overall structure of FGF2-STAB is similar to FGF2-wt and does not reveal information on the experimentally observed lower dependence on heparin. A noticeable difference in flexibility in the receptor binding region can explain the differences in signaling between FGF2-STAB and its wild-type counterpart. Our structural analysis provided molecular insights into the stabilization and unique biological properties of FGF2-STAB.
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spelling doaj-art-4ac9464e85cb425fb008c0c9b8444e8b2024-12-12T05:22:35ZengElsevierJournal of Structural Biology: X2590-15242024-12-0110100112Structural analysis of the stable form of fibroblast growth factor 2 – FGF2-STABGabin de La Bourdonnaye0Martin Marek1Tereza Ghazalova2Jiri Damborsky3Petr Pachl4Jiri Brynda5Veronika Stepankova6Radka Chaloupkova7Loschmidt Laboratories, Department of Experimental Biology and RECETOX, Faculty of Science, Masaryk University, Brno, Czech Republic; Enantis Ltd., Biotechnology Incubator INBIT, Brno, Czech RepublicLoschmidt Laboratories, Department of Experimental Biology and RECETOX, Faculty of Science, Masaryk University, Brno, Czech Republic; International Clinical Research Center, St. Anne’s University Hospital, Brno, Czech RepublicEnantis Ltd., Biotechnology Incubator INBIT, Brno, Czech RepublicLoschmidt Laboratories, Department of Experimental Biology and RECETOX, Faculty of Science, Masaryk University, Brno, Czech Republic; International Clinical Research Center, St. Anne’s University Hospital, Brno, Czech RepublicInstitute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Prague, Czech RepublicInstitute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Prague, Czech RepublicEnantis Ltd., Biotechnology Incubator INBIT, Brno, Czech RepublicLoschmidt Laboratories, Department of Experimental Biology and RECETOX, Faculty of Science, Masaryk University, Brno, Czech Republic; Enantis Ltd., Biotechnology Incubator INBIT, Brno, Czech Republic; Corresponding author.Fibroblast growth factor 2 (FGF2) is a signaling protein that plays a significant role in tissue development and repair. FGF2 binds to fibroblast growth factor receptors (FGFRs) alongside its co-factor heparin, which protects FGF2 from degradation. The binding between FGF2 and FGFRs induces intracellular signaling pathways such as RAS-MAPK, PI3K-AKT, and STAT. FGF2 has strong potential for application in cell culturing, wound healing, and cosmetics but the potential is severely limited by its low protein stability. The thermostable variant FGF2-STAB was constructed by computer-assisted protein engineering to overcome the natural limitation of FGF2. Previously reported characterization of FGF2-STAB revealed an enhanced ability to induce MAP/ERK signaling while having a lower dependence on heparin when compared with FGF2-wt. Here we report the crystal structure of FGF2-STAB solved at 1.3 Å resolution. Protein stabilization is achieved by newly formed hydrophobic interactions, polar contacts, and one additional hydrogen bond. The overall structure of FGF2-STAB is similar to FGF2-wt and does not reveal information on the experimentally observed lower dependence on heparin. A noticeable difference in flexibility in the receptor binding region can explain the differences in signaling between FGF2-STAB and its wild-type counterpart. Our structural analysis provided molecular insights into the stabilization and unique biological properties of FGF2-STAB.http://www.sciencedirect.com/science/article/pii/S2590152424000175Stabilized fibroblast growth factor 2X-ray structural analysisProtein flexibility
spellingShingle Gabin de La Bourdonnaye
Martin Marek
Tereza Ghazalova
Jiri Damborsky
Petr Pachl
Jiri Brynda
Veronika Stepankova
Radka Chaloupkova
Structural analysis of the stable form of fibroblast growth factor 2 – FGF2-STAB
Journal of Structural Biology: X
Stabilized fibroblast growth factor 2
X-ray structural analysis
Protein flexibility
title Structural analysis of the stable form of fibroblast growth factor 2 – FGF2-STAB
title_full Structural analysis of the stable form of fibroblast growth factor 2 – FGF2-STAB
title_fullStr Structural analysis of the stable form of fibroblast growth factor 2 – FGF2-STAB
title_full_unstemmed Structural analysis of the stable form of fibroblast growth factor 2 – FGF2-STAB
title_short Structural analysis of the stable form of fibroblast growth factor 2 – FGF2-STAB
title_sort structural analysis of the stable form of fibroblast growth factor 2 fgf2 stab
topic Stabilized fibroblast growth factor 2
X-ray structural analysis
Protein flexibility
url http://www.sciencedirect.com/science/article/pii/S2590152424000175
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