Insights from the compositional evolution of a multi-coloured, zoned tourmaline from the Cruzeiro pegmatite, Minas Gerais, Brazil
<p>This study compares the compositional evolution of a multi-coloured, zoned tourmaline crystal from the Cruzeiro pegmatite, Brazil, with the compositions of homogeneous tourmaline crystals systematically collected from the outer to the inner zones of the same pegmatite. Four representative f...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Copernicus Publications
2025-01-01
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| Series: | European Journal of Mineralogy |
| Online Access: | https://ejm.copernicus.org/articles/37/1/2025/ejm-37-1-2025.pdf |
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| Summary: | <p>This study compares the compositional evolution of a multi-coloured, zoned tourmaline crystal from the Cruzeiro pegmatite, Brazil, with the compositions of homogeneous tourmaline crystals systematically collected from the outer to the inner zones of the same pegmatite. Four representative fragments of the multi-coloured, zoned tourmaline were thoroughly investigated using single-crystal X-ray diffraction; electron microprobe analysis; and <span class="inline-formula"><sup>57</sup></span>Fe Mössbauer, Fourier transform infrared, and optical absorption spectroscopies to obtain the full composition and site occupancies. The fragments are classified, from core to rim, as <span class="inline-formula"><sup>W</sup></span>O-rich, F-bearing schorl (black inner and outer core) and Fe<span class="inline-formula"><sup>2+</sup></span>-rich, <span class="inline-formula"><sup>W</sup></span>OH-bearing fluor-elbaite (blue inner and green outer rim). A negative correlation between F and Fe<span class="inline-formula"><sup>2+</sup></span> contents was evidenced, approximated by the equation F <span class="inline-formula">=</span> 1 <span class="inline-formula">−</span> 0.33Fe<span class="inline-formula"><sup>2+</sup></span> (in atoms per formula unit) and consistent with the observed tourmaline evolution from schorl to fluor-elbaite.</p>
<p>The evolution trend from core to rim mirrors the compositional variation exhibited by the homogeneous tourmaline crystals collected across the Cruzeiro pegmatite, from the border zone to the intermediate zone. This shows that the chemical variations in a zoned tourmaline, observed at the scale of single crystals, record not only its crystal growth history, but also the chemical evolution of the host pegmatite. Moreover, in uncontaminated granitic pegmatite systems such as that of Cruzeiro, the compositional evolution of tourmaline progresses from schorl to fluor-elbaite, rather than from schorl to elbaite, to reflect co-enrichment in Li and F during fractional crystallization.</p> |
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| ISSN: | 0935-1221 1617-4011 |