Combination of fluorescent and spin labels: a powerful method for the optimization of hydrophilic membranes for the separation of oil-in-water emulsions

A new method for assessing the quality of fibre coating based on a combination of fluorescence microscopy and electron paramagnetic resonance is presented in this work. An influence of the carboxymethylcellulose/polyvinylamine gel preparation method on the mobility of the spin label was established....

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Main Authors: Rita S. Alqubelat, Alena D. Kuznetsova, Denis O. Antonov, Maxim A. Mironov
Format: Article
Language:English
Published: Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina 2023-12-01
Series:Chimica Techno Acta
Subjects:
Online Access:https://chimicatechnoacta.ru/article/view/7261
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author Rita S. Alqubelat
Alena D. Kuznetsova
Denis O. Antonov
Maxim A. Mironov
author_facet Rita S. Alqubelat
Alena D. Kuznetsova
Denis O. Antonov
Maxim A. Mironov
author_sort Rita S. Alqubelat
collection DOAJ
description A new method for assessing the quality of fibre coating based on a combination of fluorescence microscopy and electron paramagnetic resonance is presented in this work. An influence of the carboxymethylcellulose/polyvinylamine gel preparation method on the mobility of the spin label was established. The mobility of the spin label changes from 3.5 ns in the case of a polyvinylamine solution to 12.8 ns in the case of a cross-linked gel on the surface of the glass fibre. A qualitative relationship was found between the mobility of the spin label in the gel applied to the glass fibre and the rate of spreading of crude oil over its surface. This method can be used to make membranes for the separation of water-in-oil emulsions.
format Article
id doaj-art-47b2a8822bc146b3954fbf1d15d8aef5
institution Kabale University
issn 2411-1414
language English
publishDate 2023-12-01
publisher Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
record_format Article
series Chimica Techno Acta
spelling doaj-art-47b2a8822bc146b3954fbf1d15d8aef52024-12-25T09:36:55ZengUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. ElʹcinaChimica Techno Acta2411-14142023-12-0110410.15826/chimtech.2023.10.4.155125Combination of fluorescent and spin labels: a powerful method for the optimization of hydrophilic membranes for the separation of oil-in-water emulsionsRita S. Alqubelat0Alena D. Kuznetsova1Denis O. Antonov2Maxim A. Mironov3Ural Federal UniversityUral Federal UniversityI. Ya. Postovsky Institute of Organic Synthesis, UB RASUral Federal UniversityA new method for assessing the quality of fibre coating based on a combination of fluorescence microscopy and electron paramagnetic resonance is presented in this work. An influence of the carboxymethylcellulose/polyvinylamine gel preparation method on the mobility of the spin label was established. The mobility of the spin label changes from 3.5 ns in the case of a polyvinylamine solution to 12.8 ns in the case of a cross-linked gel on the surface of the glass fibre. A qualitative relationship was found between the mobility of the spin label in the gel applied to the glass fibre and the rate of spreading of crude oil over its surface. This method can be used to make membranes for the separation of water-in-oil emulsions.https://chimicatechnoacta.ru/article/view/7261fluorescent labelspin labeloil-in-water emulsioncarboxymethylcellulosepolyvinylamine
spellingShingle Rita S. Alqubelat
Alena D. Kuznetsova
Denis O. Antonov
Maxim A. Mironov
Combination of fluorescent and spin labels: a powerful method for the optimization of hydrophilic membranes for the separation of oil-in-water emulsions
Chimica Techno Acta
fluorescent label
spin label
oil-in-water emulsion
carboxymethylcellulose
polyvinylamine
title Combination of fluorescent and spin labels: a powerful method for the optimization of hydrophilic membranes for the separation of oil-in-water emulsions
title_full Combination of fluorescent and spin labels: a powerful method for the optimization of hydrophilic membranes for the separation of oil-in-water emulsions
title_fullStr Combination of fluorescent and spin labels: a powerful method for the optimization of hydrophilic membranes for the separation of oil-in-water emulsions
title_full_unstemmed Combination of fluorescent and spin labels: a powerful method for the optimization of hydrophilic membranes for the separation of oil-in-water emulsions
title_short Combination of fluorescent and spin labels: a powerful method for the optimization of hydrophilic membranes for the separation of oil-in-water emulsions
title_sort combination of fluorescent and spin labels a powerful method for the optimization of hydrophilic membranes for the separation of oil in water emulsions
topic fluorescent label
spin label
oil-in-water emulsion
carboxymethylcellulose
polyvinylamine
url https://chimicatechnoacta.ru/article/view/7261
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AT alenadkuznetsova combinationoffluorescentandspinlabelsapowerfulmethodfortheoptimizationofhydrophilicmembranesfortheseparationofoilinwateremulsions
AT denisoantonov combinationoffluorescentandspinlabelsapowerfulmethodfortheoptimizationofhydrophilicmembranesfortheseparationofoilinwateremulsions
AT maximamironov combinationoffluorescentandspinlabelsapowerfulmethodfortheoptimizationofhydrophilicmembranesfortheseparationofoilinwateremulsions