Resolving the Relaxation of Volatile Valence Change Memory

Abstract Memristive devices based on the valence change mechanism are highly interesting candidates for data storage and hardware implementation of synapses in neuromorphic circuits. Although long‐term retention is often required for data storage applications, a slight resistance drift of the low re...

Full description

Saved in:
Bibliographic Details
Main Authors: Johannes Hellwig, Carsten Funck, Sebastian Siegel, Alexandros Sarantopoulos, Dimitrios Spithouris, Stephan Menzel, Regina Dittmann
Format: Article
Language:English
Published: Wiley-VCH 2024-12-01
Series:Advanced Electronic Materials
Subjects:
Online Access:https://doi.org/10.1002/aelm.202400062
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1841553142783672320
author Johannes Hellwig
Carsten Funck
Sebastian Siegel
Alexandros Sarantopoulos
Dimitrios Spithouris
Stephan Menzel
Regina Dittmann
author_facet Johannes Hellwig
Carsten Funck
Sebastian Siegel
Alexandros Sarantopoulos
Dimitrios Spithouris
Stephan Menzel
Regina Dittmann
author_sort Johannes Hellwig
collection DOAJ
description Abstract Memristive devices based on the valence change mechanism are highly interesting candidates for data storage and hardware implementation of synapses in neuromorphic circuits. Although long‐term retention is often required for data storage applications, a slight resistance drift of the low resistive state (LRS) is observed even for stable devices. For other devices, the LRS has been observed to decay rapidly to the high resistive state (HRS). These types of devices are of interest for neuromorphic circuits where short‐term plasticity is required. In this work, the LRS relaxation of volatile, crystalline Pt/SrTiO3/Nb:SrTiO3: devices is investigated in detail, yielding time constants ranging from milliseconds to seconds. The decay is analyzed in terms of the Gibbs free energy gradient for the contribution of oxygen ion migration. A relaxation model based on drift‐diffusion dynamics is presented. The model may serve as a tool for developing guidelines and design rules for future volatile memristive technology based on Schottky barrier mediated electron transport.
format Article
id doaj-art-456a494925984651bab6972d62408ace
institution Kabale University
issn 2199-160X
language English
publishDate 2024-12-01
publisher Wiley-VCH
record_format Article
series Advanced Electronic Materials
spelling doaj-art-456a494925984651bab6972d62408ace2025-01-09T11:51:13ZengWiley-VCHAdvanced Electronic Materials2199-160X2024-12-011012n/an/a10.1002/aelm.202400062Resolving the Relaxation of Volatile Valence Change MemoryJohannes Hellwig0Carsten Funck1Sebastian Siegel2Alexandros Sarantopoulos3Dimitrios Spithouris4Stephan Menzel5Regina Dittmann6Forschungszentrum Jülich Gmbh PGI‐7 & JARA‐FIT 52428 Jülich GermanyForschungszentrum Jülich Gmbh PGI‐7 & JARA‐FIT 52428 Jülich GermanyForschungszentrum Jülich Gmbh PGI‐7 & JARA‐FIT 52428 Jülich GermanyForschungszentrum Jülich Gmbh PGI‐7 & JARA‐FIT 52428 Jülich GermanyForschungszentrum Jülich Gmbh PGI‐7 & JARA‐FIT 52428 Jülich GermanyForschungszentrum Jülich Gmbh PGI‐7 & JARA‐FIT 52428 Jülich GermanyForschungszentrum Jülich Gmbh PGI‐7 & JARA‐FIT 52428 Jülich GermanyAbstract Memristive devices based on the valence change mechanism are highly interesting candidates for data storage and hardware implementation of synapses in neuromorphic circuits. Although long‐term retention is often required for data storage applications, a slight resistance drift of the low resistive state (LRS) is observed even for stable devices. For other devices, the LRS has been observed to decay rapidly to the high resistive state (HRS). These types of devices are of interest for neuromorphic circuits where short‐term plasticity is required. In this work, the LRS relaxation of volatile, crystalline Pt/SrTiO3/Nb:SrTiO3: devices is investigated in detail, yielding time constants ranging from milliseconds to seconds. The decay is analyzed in terms of the Gibbs free energy gradient for the contribution of oxygen ion migration. A relaxation model based on drift‐diffusion dynamics is presented. The model may serve as a tool for developing guidelines and design rules for future volatile memristive technology based on Schottky barrier mediated electron transport.https://doi.org/10.1002/aelm.202400062memristive deviceretentionVCM
spellingShingle Johannes Hellwig
Carsten Funck
Sebastian Siegel
Alexandros Sarantopoulos
Dimitrios Spithouris
Stephan Menzel
Regina Dittmann
Resolving the Relaxation of Volatile Valence Change Memory
Advanced Electronic Materials
memristive device
retention
VCM
title Resolving the Relaxation of Volatile Valence Change Memory
title_full Resolving the Relaxation of Volatile Valence Change Memory
title_fullStr Resolving the Relaxation of Volatile Valence Change Memory
title_full_unstemmed Resolving the Relaxation of Volatile Valence Change Memory
title_short Resolving the Relaxation of Volatile Valence Change Memory
title_sort resolving the relaxation of volatile valence change memory
topic memristive device
retention
VCM
url https://doi.org/10.1002/aelm.202400062
work_keys_str_mv AT johanneshellwig resolvingtherelaxationofvolatilevalencechangememory
AT carstenfunck resolvingtherelaxationofvolatilevalencechangememory
AT sebastiansiegel resolvingtherelaxationofvolatilevalencechangememory
AT alexandrossarantopoulos resolvingtherelaxationofvolatilevalencechangememory
AT dimitriosspithouris resolvingtherelaxationofvolatilevalencechangememory
AT stephanmenzel resolvingtherelaxationofvolatilevalencechangememory
AT reginadittmann resolvingtherelaxationofvolatilevalencechangememory