SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMS
First, phenol thiazine is reacted with sodium metabisulphite, sodium cyanide, and 4-Formylbenzonitrile to yield the appropriate nitrile. In this study, 4-(cyano(10H-phenothiazin-10-yl)methyl)benzonitrile, a phenothiazine derivative, was synthesized. The stereoscopic shape of the complexes formed aro...
Saved in:
Main Authors: | , , |
---|---|
Format: | Article |
Language: | Arabic |
Published: |
University of Anbar
2024-12-01
|
Series: | مجلة الأنبار للعلوم الزراعية |
Subjects: | |
Online Access: | https://ajas.uoanbar.edu.iq/article_184468_4e5098c29621d9202c356df0353403c5.pdf |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
_version_ | 1841545648542842880 |
---|---|
author | G. Sh. Al-Obaidy H. Kh. Kh. Al-Dulymi M. A. Abed |
author_facet | G. Sh. Al-Obaidy H. Kh. Kh. Al-Dulymi M. A. Abed |
author_sort | G. Sh. Al-Obaidy |
collection | DOAJ |
description | First, phenol thiazine is reacted with sodium metabisulphite, sodium cyanide, and 4-Formylbenzonitrile to yield the appropriate nitrile. In this study, 4-(cyano(10H-phenothiazin-10-yl)methyl)benzonitrile, a phenothiazine derivative, was synthesized. The stereoscopic shape of the complexes formed around the ionic centers was determined using spectroscopic and physical techniques, including elemental analysis, 1H-NMR and 13C- NMR spectra, FTIR, UV-Vis, metal content, and conductance measurements. After synthesizing the derivatives of the complexes the biological activity of the prepared ligand and its complexes was studied to estimate their potential antimicrobial activity. In general, tests show the ligand and its complexes having good activity against bacteria. The prepared ligand was used to remove heavy metals causing water pollution. Among the heavy elements studied were zinc, lead, and copper. The findings suggest that the prepared complexes may be used to lower concentrations of these elements in water and mitigate their impact on the environment. |
format | Article |
id | doaj-art-3c66b683420f4d42bf25cb7b4d03abbd |
institution | Kabale University |
issn | 1992-7479 2617-6211 |
language | Arabic |
publishDate | 2024-12-01 |
publisher | University of Anbar |
record_format | Article |
series | مجلة الأنبار للعلوم الزراعية |
spelling | doaj-art-3c66b683420f4d42bf25cb7b4d03abbd2025-01-11T22:05:11ZaraUniversity of Anbarمجلة الأنبار للعلوم الزراعية1992-74792617-62112024-12-012221082109310.32649/ajas.2024.184468184468SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMSG. Sh. Al-Obaidy0H. Kh. Kh. Al-Dulymi1M. A. Abed2Department of Chemistry, College of Science, University of AnbarDepartment of Chemistry, College of Science, University of AnbarDepartment of Food Sciences, College of Agriculture, University of AnbarFirst, phenol thiazine is reacted with sodium metabisulphite, sodium cyanide, and 4-Formylbenzonitrile to yield the appropriate nitrile. In this study, 4-(cyano(10H-phenothiazin-10-yl)methyl)benzonitrile, a phenothiazine derivative, was synthesized. The stereoscopic shape of the complexes formed around the ionic centers was determined using spectroscopic and physical techniques, including elemental analysis, 1H-NMR and 13C- NMR spectra, FTIR, UV-Vis, metal content, and conductance measurements. After synthesizing the derivatives of the complexes the biological activity of the prepared ligand and its complexes was studied to estimate their potential antimicrobial activity. In general, tests show the ligand and its complexes having good activity against bacteria. The prepared ligand was used to remove heavy metals causing water pollution. Among the heavy elements studied were zinc, lead, and copper. The findings suggest that the prepared complexes may be used to lower concentrations of these elements in water and mitigate their impact on the environment.https://ajas.uoanbar.edu.iq/article_184468_4e5098c29621d9202c356df0353403c5.pdftransition metal complexesphysical techniquesspectral characterization |
spellingShingle | G. Sh. Al-Obaidy H. Kh. Kh. Al-Dulymi M. A. Abed SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMS مجلة الأنبار للعلوم الزراعية transition metal complexes physical techniques spectral characterization |
title | SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMS |
title_full | SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMS |
title_fullStr | SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMS |
title_full_unstemmed | SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMS |
title_short | SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMS |
title_sort | synthesizing pd ii ru ii benzonitrile phenothiazine derivative complexes and investigating their antibacterial activity and removal of some heavy metals in environmental systems |
topic | transition metal complexes physical techniques spectral characterization |
url | https://ajas.uoanbar.edu.iq/article_184468_4e5098c29621d9202c356df0353403c5.pdf |
work_keys_str_mv | AT gshalobaidy synthesizingpdiiruiibenzonitrilephenothiazinederivativecomplexesandinvestigatingtheirantibacterialactivityandremovalofsomeheavymetalsinenvironmentalsystems AT hkhkhaldulymi synthesizingpdiiruiibenzonitrilephenothiazinederivativecomplexesandinvestigatingtheirantibacterialactivityandremovalofsomeheavymetalsinenvironmentalsystems AT maabed synthesizingpdiiruiibenzonitrilephenothiazinederivativecomplexesandinvestigatingtheirantibacterialactivityandremovalofsomeheavymetalsinenvironmentalsystems |