SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMS

First, phenol thiazine is reacted with sodium metabisulphite, sodium cyanide, and 4-Formylbenzonitrile to yield the appropriate nitrile. In this study, 4-(cyano(10H-phenothiazin-10-yl)methyl)benzonitrile, a phenothiazine derivative, was synthesized. The stereoscopic shape of the complexes formed aro...

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Main Authors: G. Sh. Al-Obaidy, H. Kh. Kh. Al-Dulymi, M. A. Abed
Format: Article
Language:Arabic
Published: University of Anbar 2024-12-01
Series:مجلة الأنبار للعلوم الزراعية
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Online Access:https://ajas.uoanbar.edu.iq/article_184468_4e5098c29621d9202c356df0353403c5.pdf
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author G. Sh. Al-Obaidy
H. Kh. Kh. Al-Dulymi
M. A. Abed
author_facet G. Sh. Al-Obaidy
H. Kh. Kh. Al-Dulymi
M. A. Abed
author_sort G. Sh. Al-Obaidy
collection DOAJ
description First, phenol thiazine is reacted with sodium metabisulphite, sodium cyanide, and 4-Formylbenzonitrile to yield the appropriate nitrile. In this study, 4-(cyano(10H-phenothiazin-10-yl)methyl)benzonitrile, a phenothiazine derivative, was synthesized. The stereoscopic shape of the complexes formed around the ionic centers was determined using spectroscopic and physical techniques, including elemental analysis, 1H-NMR and 13C- NMR spectra, FTIR, UV-Vis, metal content, and conductance measurements. After synthesizing the derivatives of the complexes the biological activity of the prepared ligand and its complexes was studied to estimate their potential antimicrobial activity. In general, tests show the ligand and its complexes having good activity against bacteria. The prepared ligand was used to remove heavy metals causing water pollution. Among the heavy elements studied were zinc, lead, and copper. The findings suggest that the prepared complexes may be used to lower concentrations of these elements in water and mitigate their impact on the environment.
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institution Kabale University
issn 1992-7479
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publishDate 2024-12-01
publisher University of Anbar
record_format Article
series مجلة الأنبار للعلوم الزراعية
spelling doaj-art-3c66b683420f4d42bf25cb7b4d03abbd2025-01-11T22:05:11ZaraUniversity of Anbarمجلة الأنبار للعلوم الزراعية1992-74792617-62112024-12-012221082109310.32649/ajas.2024.184468184468SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMSG. Sh. Al-Obaidy0H. Kh. Kh. Al-Dulymi1M. A. Abed2Department of Chemistry, College of Science, University of AnbarDepartment of Chemistry, College of Science, University of AnbarDepartment of Food Sciences, College of Agriculture, University of AnbarFirst, phenol thiazine is reacted with sodium metabisulphite, sodium cyanide, and 4-Formylbenzonitrile to yield the appropriate nitrile. In this study, 4-(cyano(10H-phenothiazin-10-yl)methyl)benzonitrile, a phenothiazine derivative, was synthesized. The stereoscopic shape of the complexes formed around the ionic centers was determined using spectroscopic and physical techniques, including elemental analysis, 1H-NMR and 13C- NMR spectra, FTIR, UV-Vis, metal content, and conductance measurements. After synthesizing the derivatives of the complexes the biological activity of the prepared ligand and its complexes was studied to estimate their potential antimicrobial activity. In general, tests show the ligand and its complexes having good activity against bacteria. The prepared ligand was used to remove heavy metals causing water pollution. Among the heavy elements studied were zinc, lead, and copper. The findings suggest that the prepared complexes may be used to lower concentrations of these elements in water and mitigate their impact on the environment.https://ajas.uoanbar.edu.iq/article_184468_4e5098c29621d9202c356df0353403c5.pdftransition metal complexesphysical techniquesspectral characterization
spellingShingle G. Sh. Al-Obaidy
H. Kh. Kh. Al-Dulymi
M. A. Abed
SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMS
مجلة الأنبار للعلوم الزراعية
transition metal complexes
physical techniques
spectral characterization
title SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMS
title_full SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMS
title_fullStr SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMS
title_full_unstemmed SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMS
title_short SYNTHESIZING PD (II), RU (II) BENZONITRILE-PHENOTHIAZINE DERIVATIVE COMPLEXES AND INVESTIGATING THEIR ANTIBACTERIAL ACTIVITY AND REMOVAL OF SOME HEAVY METALS IN ENVIRONMENTAL SYSTEMS
title_sort synthesizing pd ii ru ii benzonitrile phenothiazine derivative complexes and investigating their antibacterial activity and removal of some heavy metals in environmental systems
topic transition metal complexes
physical techniques
spectral characterization
url https://ajas.uoanbar.edu.iq/article_184468_4e5098c29621d9202c356df0353403c5.pdf
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