Production of Hydrogen from Biomass with Negative CO<sub>2</sub> Emissions Using a Commercial-Scale Fluidized Bed Gasifier

Biomass gasification, as a thermochemical method, has attracted interest due to the growing popularity of biofuel production using syngas or pure hydrogen. Additionally, this hydrogen production method, when integrated with CO<sub>2</sub> capture, may have negative CO<sub>2</sub...

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Bibliographic Details
Main Authors: Tomasz Chmielniak, Tomasz Iluk, Leszek Stepien, Tomasz Billig, Marek Sciazko
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Energies
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Online Access:https://www.mdpi.com/1996-1073/17/22/5591
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Summary:Biomass gasification, as a thermochemical method, has attracted interest due to the growing popularity of biofuel production using syngas or pure hydrogen. Additionally, this hydrogen production method, when integrated with CO<sub>2</sub> capture, may have negative CO<sub>2</sub> emissions, which makes this process competitive with electrolysis and coal gasification. This article presents the results of process and economic analyses of a hydrogen production system integrated with a commercial, fluidized-bed solid fuel gasification reactor (SES technology—Synthesis Energy Systems). With the use of a single gasification unit with a capacity of 60 t/h of raw biomass, the system produces between 72.5 and 78.4 t/d of hydrogen depending on the configuration considered. Additionally, assuming the CO<sub>2</sub> emission neutrality of biomass processing, the application of CO<sub>2</sub> capture leads to negative CO<sub>2</sub> emissions. This allows for obtaining additional revenue from the sale of CO<sub>2</sub> emission allowances, which can significantly reduce the costs of hydrogen production. In this analysis, the breakthrough price for CO<sub>2</sub> emissions, above which the hydrogen production costs are negative, is USD 240/t CO<sub>2</sub>.
ISSN:1996-1073