Post-Processing Thermal Activation of Thermoelectric Materials Based on Germanium

After the deposition process, the lattice structure of doped germanium remains low. Post-processing annealing reorders the structure and increases the output parameters. Thin films of germanium doped with gold (Ge:Au) and vanadium (Ge:V) were magnetron-sputtered on glass substrates. The course of th...

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Main Authors: Piotr Marek Markowski, Eugeniusz Prociów
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/18/1/65
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author Piotr Marek Markowski
Eugeniusz Prociów
author_facet Piotr Marek Markowski
Eugeniusz Prociów
author_sort Piotr Marek Markowski
collection DOAJ
description After the deposition process, the lattice structure of doped germanium remains low. Post-processing annealing reorders the structure and increases the output parameters. Thin films of germanium doped with gold (Ge:Au) and vanadium (Ge:V) were magnetron-sputtered on glass substrates. The course of the activation process was monitored in situ. Two different methods of post-processing thermal activation of the films were studied. The first method was to place the structure at an elevated temperature for a specified period of time. The second method involved placing the structure on a heating table and cycling the heating and cooling several times from room temperature to about 823 K. Both methods fulfill their function well. The differences come down to research aspects. The best thermoelectric parameters were achieved for germanium doped with 0.95 at.% vanadium. The Seebeck coefficient of 212 μV/K and the power factor of 1.24 mW·m<sup>−1</sup>·K<sup>−2</sup> were obtained at 500 K.
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spelling doaj-art-2039087075834aaba801859a13e143112025-01-10T13:16:59ZengMDPI AGEnergies1996-10732024-12-011816510.3390/en18010065Post-Processing Thermal Activation of Thermoelectric Materials Based on GermaniumPiotr Marek Markowski0Eugeniusz Prociów1Faculty of Electronics, Photonics and Microsystems, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, PolandFaculty of Electronics, Photonics and Microsystems, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, PolandAfter the deposition process, the lattice structure of doped germanium remains low. Post-processing annealing reorders the structure and increases the output parameters. Thin films of germanium doped with gold (Ge:Au) and vanadium (Ge:V) were magnetron-sputtered on glass substrates. The course of the activation process was monitored in situ. Two different methods of post-processing thermal activation of the films were studied. The first method was to place the structure at an elevated temperature for a specified period of time. The second method involved placing the structure on a heating table and cycling the heating and cooling several times from room temperature to about 823 K. Both methods fulfill their function well. The differences come down to research aspects. The best thermoelectric parameters were achieved for germanium doped with 0.95 at.% vanadium. The Seebeck coefficient of 212 μV/K and the power factor of 1.24 mW·m<sup>−1</sup>·K<sup>−2</sup> were obtained at 500 K.https://www.mdpi.com/1996-1073/18/1/65thermoelectricsSeebeck coefficientgermaniumthin filmmagnetron sputteringpost processing annealing
spellingShingle Piotr Marek Markowski
Eugeniusz Prociów
Post-Processing Thermal Activation of Thermoelectric Materials Based on Germanium
Energies
thermoelectrics
Seebeck coefficient
germanium
thin film
magnetron sputtering
post processing annealing
title Post-Processing Thermal Activation of Thermoelectric Materials Based on Germanium
title_full Post-Processing Thermal Activation of Thermoelectric Materials Based on Germanium
title_fullStr Post-Processing Thermal Activation of Thermoelectric Materials Based on Germanium
title_full_unstemmed Post-Processing Thermal Activation of Thermoelectric Materials Based on Germanium
title_short Post-Processing Thermal Activation of Thermoelectric Materials Based on Germanium
title_sort post processing thermal activation of thermoelectric materials based on germanium
topic thermoelectrics
Seebeck coefficient
germanium
thin film
magnetron sputtering
post processing annealing
url https://www.mdpi.com/1996-1073/18/1/65
work_keys_str_mv AT piotrmarekmarkowski postprocessingthermalactivationofthermoelectricmaterialsbasedongermanium
AT eugeniuszprociow postprocessingthermalactivationofthermoelectricmaterialsbasedongermanium