Synthesis and olfactory evaluation of (±)-β-irone

Abstract The powdery scent of orris root oil adds elegance and depth to any fragrance. However, orris root oil is one of the most expensive essential oils due to a lengthy six-year production process. If compounds with the powdery scent could be supplied by chemical synthesis at a lower cost than na...

Full description

Saved in:
Bibliographic Details
Main Authors: Shigekazu Yamazaki, Makoto Miyazaki
Format: Article
Language:English
Published: Nature Portfolio 2025-07-01
Series:Scientific Reports
Subjects:
Online Access:https://doi.org/10.1038/s41598-025-08925-z
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Abstract The powdery scent of orris root oil adds elegance and depth to any fragrance. However, orris root oil is one of the most expensive essential oils due to a lengthy six-year production process. If compounds with the powdery scent could be supplied by chemical synthesis at a lower cost than natural products, there would be a large demand. In the course of our research into the synthesis and olfactory evaluation of irone isomers, we found that (±)-β-irone, a minor component of orris root oil, has an excellent powdery aroma. In this study, we report a new synthetic method for (±)-β-irone and the results of its olfactory evaluation. The synthesis of (±)-β-irone was accomplished using commercially available 3-methylcyclohexanone as the starting material. The olfactory evaluation of synthesized (±)-β-irone was performed. (±)-β-Irone has been found to have a strong, transparent, fruity green top note, a rich violet floral heart note, and a clear, powerful, and long-lasting powdery last note with a woody odor. We considered that some part of the powdery fragrance of orris root oil originates from β-irone, and that β-irone is an excellent flavoring and fragrance material that can be used as a substitute for natural orris root oil.
ISSN:2045-2322