Transparent electro-optic ceramics: Processing, materials, and applications

Transparent electro-optic (EO) oxide ceramics are known for their rapid EO effects. EO ceramics have several advantages over single-crystals, including variable size and shape, controllable chemical composition, superior mechanical properties, and low cost. Synthesis of high-performance transparent...

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Main Authors: Iva Milisavljevic, Man Zhang, Qinghui Jiang, Qing Liu, Yiquan Wu
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Journal of Materiomics
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Online Access:http://www.sciencedirect.com/science/article/pii/S235284782400087X
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author Iva Milisavljevic
Man Zhang
Qinghui Jiang
Qing Liu
Yiquan Wu
author_facet Iva Milisavljevic
Man Zhang
Qinghui Jiang
Qing Liu
Yiquan Wu
author_sort Iva Milisavljevic
collection DOAJ
description Transparent electro-optic (EO) oxide ceramics are known for their rapid EO effects. EO ceramics have several advantages over single-crystals, including variable size and shape, controllable chemical composition, superior mechanical properties, and low cost. Synthesis of high-performance transparent EO ceramics requires high purity of raw materials, high density, homogeneous composition, uniform grain size, and relatively wide bandgap. Powder synthesis and sintering are two of the critical steps involved in the fabrication of highly transparent EO ceramics. Using high-activity precursor powders has been effective in fabricating high-density ceramics that demonstrate excellent EO performance. The sintering process plays a crucial role in achieving this result, and currently, there are several sintering methods available for producing high-density ceramics, including hot-pressing, hot isostatic pressing, and spark plasma sintering. This review summarizes the recent progress in materials and processes used to develop transparent EO ceramics, including those based on lead zirconate titanate, lead magnesium niobate-lead titanate, and lead-free potassium sodium niobate. In addition, several novel applications of transparent EO ceramics, including light shutters, spectral filters, optical memory, as well as image storage and displays are reviewed. In the end, the review concludes with a discussion of future trends and perspectives.
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institution Kabale University
issn 2352-8478
language English
publishDate 2025-03-01
publisher Elsevier
record_format Article
series Journal of Materiomics
spelling doaj-art-16cc9918ec2b448e90e90aa67c4343552025-01-14T04:12:27ZengElsevierJournal of Materiomics2352-84782025-03-01112100872Transparent electro-optic ceramics: Processing, materials, and applicationsIva Milisavljevic0Man Zhang1Qinghui Jiang2Qing Liu3Yiquan Wu4Kazuo Inamori School of Engineering, New York State College of Ceramics, Alfred University, Alfred, NY 14802, USASchool of Mechanical Engineering, University of Leeds, Woodhouse Lane, Leeds, LS2 9JT, UKSchool of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074, ChinaSchool of Optoelectronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu, 611731, ChinaKazuo Inamori School of Engineering, New York State College of Ceramics, Alfred University, Alfred, NY 14802, USA; Corresponding author.Transparent electro-optic (EO) oxide ceramics are known for their rapid EO effects. EO ceramics have several advantages over single-crystals, including variable size and shape, controllable chemical composition, superior mechanical properties, and low cost. Synthesis of high-performance transparent EO ceramics requires high purity of raw materials, high density, homogeneous composition, uniform grain size, and relatively wide bandgap. Powder synthesis and sintering are two of the critical steps involved in the fabrication of highly transparent EO ceramics. Using high-activity precursor powders has been effective in fabricating high-density ceramics that demonstrate excellent EO performance. The sintering process plays a crucial role in achieving this result, and currently, there are several sintering methods available for producing high-density ceramics, including hot-pressing, hot isostatic pressing, and spark plasma sintering. This review summarizes the recent progress in materials and processes used to develop transparent EO ceramics, including those based on lead zirconate titanate, lead magnesium niobate-lead titanate, and lead-free potassium sodium niobate. In addition, several novel applications of transparent EO ceramics, including light shutters, spectral filters, optical memory, as well as image storage and displays are reviewed. In the end, the review concludes with a discussion of future trends and perspectives.http://www.sciencedirect.com/science/article/pii/S235284782400087XElectro-optic (EO) oxideTransparent ceramicsOptical memorySpectral filtersFerroelectric behavior
spellingShingle Iva Milisavljevic
Man Zhang
Qinghui Jiang
Qing Liu
Yiquan Wu
Transparent electro-optic ceramics: Processing, materials, and applications
Journal of Materiomics
Electro-optic (EO) oxide
Transparent ceramics
Optical memory
Spectral filters
Ferroelectric behavior
title Transparent electro-optic ceramics: Processing, materials, and applications
title_full Transparent electro-optic ceramics: Processing, materials, and applications
title_fullStr Transparent electro-optic ceramics: Processing, materials, and applications
title_full_unstemmed Transparent electro-optic ceramics: Processing, materials, and applications
title_short Transparent electro-optic ceramics: Processing, materials, and applications
title_sort transparent electro optic ceramics processing materials and applications
topic Electro-optic (EO) oxide
Transparent ceramics
Optical memory
Spectral filters
Ferroelectric behavior
url http://www.sciencedirect.com/science/article/pii/S235284782400087X
work_keys_str_mv AT ivamilisavljevic transparentelectroopticceramicsprocessingmaterialsandapplications
AT manzhang transparentelectroopticceramicsprocessingmaterialsandapplications
AT qinghuijiang transparentelectroopticceramicsprocessingmaterialsandapplications
AT qingliu transparentelectroopticceramicsprocessingmaterialsandapplications
AT yiquanwu transparentelectroopticceramicsprocessingmaterialsandapplications