Syntheses and crystal structures of (R,R)- and (S,S)-bis(acetonitrile-κN)[N,N′-dimethyl-N,N′-bis(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ4N]iron(II) bis(hexafluoroantimonate)

Syntheses and crystal structures of (R,R)- and (S,S)-bis(acetonitrile-κN)[N,N′-dimethyl-N,N′-bis(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ4N]iron(II) bis(hexafluoroantimonate)

Two enantiomeric non-heme iron complexes [Fe(R,R-BPMCN)(CH3CN)2](SbF6)2 and [Fe(S,S-BPMCN)(CH3CN)2](SbF6)2 (BPMCM = N,N′-dimethyl-N,N′-bis(pyridin-2-ylmethyl)-cyclohexane-1,2-diamine, C22H28N4) were obtained in parallel syntheses starting from the enantiomerically pure R,R and S,S BPMCN ligands. The...

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Bibliographic Details
Main Authors: Yurii S. Bibik, Iryna M. Yulakh, Svitlana V. Shishkina, Dmytro M. Khomenko, Roman O. Doroshchuk, Ilona V. Raspertova, Rostyslav D. Lampeka
Format: Article
Language:English
Published: International Union of Crystallography 2024-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
x-ray crystallography
non-heme iron catalysts
Online Access:https://journals.iucr.org/paper?S2056989024011307
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