Carbon Dioxide Capture by MgO-modified MCM-41 Materials
MgO/MCM-41 materials with weak basic sites were synthesized by dispersing MgO onto mesoporous Si-MCM-41. Such MgO-modified MCM-41 materials were characterized by Fourier-transform infrared spectroscopy (FT-IR), temperature programmed desorption (TPD), X-ray diffraction (XRD) and N 2 adsorption/desor...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
SAGE Publishing
2009-07-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/0263-6174.27.6.593 |
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| Summary: | MgO/MCM-41 materials with weak basic sites were synthesized by dispersing MgO onto mesoporous Si-MCM-41. Such MgO-modified MCM-41 materials were characterized by Fourier-transform infrared spectroscopy (FT-IR), temperature programmed desorption (TPD), X-ray diffraction (XRD) and N 2 adsorption/desorption measurements. The results indicated that the surface area, pore size and pore volume of the materials decreased with the introduction of MgO. Their CO 2 uptakes could be significantly improved when the MgO loading was increased from 0 wt% to 20 wt%. CO 2 -TPD and in situ FT-IR measurements showed that the materials possessed weak basic sites which could react with CO 2 to form bicarbonate species and thereby improve the CO 2 uptake. As a result, the adsorbed CO 2 could be desorbed completely from the sample at 200 °C. In addition, the MgO/MCM-41 materials had a high thermal stability and showed promising performances in practical applications. |
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| ISSN: | 0263-6174 2048-4038 |