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Divergent alkynylative difunctionalization of amide bonds through C–O deoxygenation versus C–N deamination
Published 2025-02-01“…Abstract The transformation and utilization of amides are significant in organic synthesis and drug discovery. Here we demonstrate a divergent alkynylative difunctionalization of amides in a single transformation. …”
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42
Tree-dimensional resources: hedgerow and orchard pollen for bumble bees
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A comprehensive review of probiotics and human health-current prospective and applications
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Thermal Synthesis of Polypeptides from N-Butyloxycarbonyl Oligopeptides Containing Aspartyl Residue at C-Terminus
Published 2017-01-01“…The thermal reactions of amino acids have been investigated for pure organic synthesis, materials preparation in industry, and prebiotic chemistry. …”
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46
Nucleophilic addition to carbonyl groups from qualitative to quantitative computational studies. A historical perspective
Published 2024-03-01“…Nucleophilic addition to carbonyl groups is one of the most important reactions in organic synthesis. In the case of a prochiral carbonyl group, the preference for the addition of a nucleophile to one face of the ${\pi }$ system leads to unequal amounts of the two possible diastereoisomers. …”
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Boosting electrocatalytic generation of FDCA and H2 from 2,5-furanedimethanol solution by carbonized wood supported Fe-CoP nanoleaves
Published 2025-01-01“…This work will pave the way towards the implementation of highly suited bifunctional electrodes and the possibility of affordable, effective, and environmentally-friendly wood-derived electrocatalysts for electrochemically organic synthesis. Graphical Abstract…”
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48
Pharmacological Profile of Quinoxalinone
Published 2014-01-01“…Quinoxalinone and its derivatives are used in organic synthesis for building natural and designed synthetic compounds and they have been frequently utilized as suitable skeletons for the design of biologically active compound. …”
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Synthesis and Reactions of Five-Membered Heterocycles Using Phase Transfer Catalyst (PTC) Techniques
Published 2014-01-01“…Application of PTC instead of traditional technologies for industrial processes of organic synthesis provides substantial benefits for the environment. …”
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Sulfonated polystyrene foam waste as an efficient catalyst for Friedel-Crafts type reactions
Published 2025-01-01“…This study highlights the potential of SPS as a sustainable and efficient catalyst, offering a greener alternative to conventional methods and promoting the valorization of plastic waste in organic synthesis.…”
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52
Research Progress on Mechanoenzymatic Reactions
Published 2024-12-01“…In recent years, in the context of global resource shortage, mechanoenzymatic reactions have attracted great attention from both academia and the food industry due to their efficient, green, energy-saving and sustainable characteristics. Organic synthesis reactions typically use a large amount of chemical reagents and require strict reaction conditions and complex downstream operations to separate and purify products, which should be used sparingly or not at all in foods. …”
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Iron-Catalyzed Cross-Dehydrogenative Coupling
Published 2025-01-01“…This method stands out for avoiding pre-functionalized substrates, reducing both waste and cost in organic synthesis. The discussion includes a variety of CDC methodologies involving combinations of C(sp<sup>3</sup>)-H with C(sp<sup>3</sup>)-H, C(sp<sup>3</sup>)-H with C(sp<sup>2</sup>)-H, and C(sp<sup>3</sup>)-H with C(sp)-H bonds. …”
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Adaptive alcohols-alcohols cross-coupling via TFA catalysis: access of unsymmetrical ethers
Published 2025-01-01“…Abstract Ethers are high value organic compounds widely applied in chemical industry, natural products, material, pharmaceuticals, argochemicals, as well as modern organic synthesis. Herein, we report an adaptive TFA-catalyzed cross-coupling of alcohols with various oxygen nucleophiles (nitro-, halogen-, sulfur-, nitrogen-, aryl-, and alkynyl-substituted aliphatic alcohols), delivering diverse unsymmetrical ethers under mild conditions and simple operation. …”
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Theoretical Study of the Chemical Properties and the Reaction Pathway of Decarbonylative Alkylative Esterification of Styrenes with Aliphatic Aldehydes
Published 2022-01-01“…Using inexpensive and available aliphatic aldehydes as an alkyl source is a useful and cost-effective way to extend the chain of benzyl esters; this decarbonylative alkylative esterification of styrene derivatives has been used for organic synthesis and medical chemistry. A cocatalyzed decarbonylative alkylative esterification of styrene derivatives with aliphatic aldehydes and iodobenzenediacetate to provide chain elongated benzoates was investigated by the density functional theory, and quantum theory of atoms in molecules analysis has been used. …”
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Anti-phenolic glycolipid antibodies in Mycobacterium bovis infected cattle
Published 2025-06-01Get full text
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Synthesis of Indole Derivatives via Aryl Triazole Ring-Opening and Subsequent Cyclization
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Synthesis and Characterization of PPV Monomer for Subsequent Electropolymerization
Published 2015-01-01“…Organic synthesis of the monomer of poly(p-phenylenevinylene) was performed starting by the 2,5-dimethylphenol compound. …”
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Ground-state flavin-dependent enzymes catalyzed enantioselective radical trifluoromethylation
Published 2025-01-01“…This strategy provides an opportunity to bridge the gap between biocatalysis and organic fluorides but also introduces an alternative approach to address challenging stereoselective fluoroalkylation reactions in organic synthesis.…”
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Weakly-Activated Phenol Derivatives as New Green Electrophilic Partners in Suzuki–Miyaura and Related C-C Couplings
Published 2024-12-01“…We hope that this article will pave the way for the development of more sustainable and efficient coupling methodologies, addressing both ecological and practical challenges in organic synthesis.…”
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