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161
A scalable solar-driven photocatalytic system for separated H2 and O2 production from water
Published 2025-01-01“…These components are bridged by a I3 −/I− redox couple to facilitate electron transfer, realizing efficient overall water splitting with a solar-to-hydrogen conversion efficiency of 2.47 ± 0.03%. …”
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162
Development of a TSR-based method for understanding structural relationships of cofactors and local environments in photosystem I
Published 2025-01-01“…(ii) There are two electron transfer chains (A and B branches) in PS I. Are the cofactors on both branches structurally different? …”
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163
Interface effects in the phase determination of Hf0.5Zr0.5O2 epitaxial thin films
Published 2025-01-01“…., La0.67Sr0.33MnO3) facilitate this electron transfer but must also have sufficient ion conductivity to support oxygen-vacancy formation in Hf0.5Zr0.5O2. …”
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164
Smaller sizes of polyethylene terephthalate microplastics mainly stimulate heterotrophic N2O production in aerobic granular sludge systems
Published 2025-05-01“…Mainstream aerobic granular sludge (AGS) systems possess potentially strong N2O-sink capability, which may be reduced by PET MPs stress through altering N2O-contributing pathways, electron transfer, and microbial community structures. …”
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165
Solanum tuberosum Leaf Extract Templated Synthesis of Co3O4 Nanoparticles for Electrochemical Sensor and Antibacterial Applications
Published 2022-01-01“…Co3O4 NPs-modified electrodes showed better sensing capability towards ascorbic acid and citric acid due to enhanced electron transfer kinetics. Among three volume ratios (1 : 2, 1 : 1, and 2 : 1) of Co3O4 nanoelectrodes, 1 : 1 and 2 : 1 were identified as the best performing nanoelectrodes. …”
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166
Single-molecule manipulation of copper nanoclusters for modulating nonlinear optics
Published 2025-03-01“…Theoretical calculations indicate that the substantial electron transfer from the PPh3 ligand to the metal core enhances the NLO performance of Cu26. …”
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167
Synthesis and Characterization of Copper Ferrite Nanoparticles for Efficient Photocatalytic Degradation of Organic Dyes
Published 2025-01-01“…A proposed mechanism involves the excitation of CuFe2O4 under visible light, facilitating electron transfer that leads to the generation of ·OH radicals, which degrade the dye molecules. …”
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168
Oncogenic mutant KRAS inhibition through oxidation at cysteine 118
Published 2025-02-01“…Specific reactive oxygen species activate the GTPase Kirsten rat sarcoma virus (KRAS) by reacting with cysteine 118 (C118), leading to an electron transfer between C118 and nucleoside guanosine diphosphate (GDP), which causes the release of GDP. …”
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169
Triplet Electron Exchange in Carbon Nanodots‐assisted Long‐persistent near‐infrared Chemiluminescence for Oncology Synergistic Imaging and Therapy
Published 2025-02-01“…Abstract In classical photodynamic therapy, tumor cells are killed by the cytotoxic species via type‐I/II photochemical reactions, seriously limited by the external photoexcitation and hypoxia. Herein, the electron transfer mechanism between fluorophores and peroxalate‐H2O2 reaction is investigated and the singlet/triplet electron exchange is utilized to achieve long‐persistent chemiluminescence imaging and synergistic type‐I/II/III photodynamic therapy. …”
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170
Comparison of enrichment methods for efficient nitrogen fixation on a biocathode
Published 2024-02-01“…It was hypothesied that autotrophic bacteria were able to use either the H2 produced at the cathode or directly the cathode through direct electron transfer (DET) as more biomass was produced than with H2 alone. …”
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171
Charge-transfer complexation of coordination cages for enhanced photochromism and photocatalysis
Published 2025-01-01“…The strong charge-transfer (CT) interactions activate guest-to-host photoinduced electron transfer (PET), leading to pronounced and regulable photochromisms. …”
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172
Electronic and photophysical properties of copper (II) Complexes: Insights into solvatochromic Effects, Photoreduction, and fluorescence behavior
Published 2025-01-01“…While HL1 exhibits a single peak, HL2 displays two peaks, findings supported by calculated transition energies and oscillator strengths.Moreover, the oxidation processes of copper complexes with iodide salt and triethylamine unveil favorable electron transfer mechanisms, as corroborated by cyclic voltammograms and free energy change values. …”
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173
Improving the power production efficiency of microbial fuel cell by using biosynthesized polyanaline coated Fe3O4 as pencil graphite anode modifier
Published 2025-01-01“…Additionally, the electrochemical behavior of the prepared nano-materials was characterized by cyclic voltammetry (CV), where low ΔEp values (0.473 V) for Fe3O4/PANI NCs indicated the presence of reversible charge transfer mechanisms at the electrode surface, reflecting a high rate of electron transfer. The synthesized nanocomposite was used to modify pencil graphite anodes to construct four single-chamber MFCs: bare pencil graphite anodes, pencil graphite anodes modified with Fe3O4, PANI, and Fe3O4/PANI nanocomposites. …”
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174
Optimization of corrosion resistance of AZ31 Mg alloy through hydration-driven interaction between quinolin-8-ol and plasma electrolytic oxidation-formed MgO layer
Published 2025-01-01“…DFT calculations further suggested that the hydration treatment provided multiple active sites, enabling effective contact with 8HQ and rapid electron transfer, creating ideal conditions for charge-transfer-induced physical and chemical bonding. …”
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175
Global proteomics and affinity mass spectrometry analysis of human Schwann cells indicates that variation in and loss of neurofibromin (NF1) alters protein expression and cellular...
Published 2025-01-01“…Finally, consistent with our proteomics findings, we show that NF1 is required to maintain mitochondrial respiratory function in Schwann cells by stabilizing NADH-linked oxidative phosphorylation and electron transfer. Taken together, these data indicate that NF1 plays a significant role in mitochondrial metabolism that results in proteomic changes in Schwann cells and may serve as a future drug target.…”
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176
Charge trapping in SiO2 substrate during electron beam deposition of CaF2 thin films of different thicknesses
Published 2025-02-01“…The relaxation of the PE spectrum intensity was attributed to electron transfer from SiO2 traps to (O2–-VA) centers. …”
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177
Toward measurements of absolute membrane potential in Bacillus subtilis using fluorescence lifetime
Published 2025-03-01“…Our method is based on 1) a unique VoltageFluor (VF) optical transducer, whose fluorescence lifetime varies as a function of MP via photoinduced electron transfer and 2) a quantitative phasor-FLIM analysis for high-throughput readout. …”
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178
Synergetic Phase Modulation and N‐Doping of MoS2 for Highly Sensitive Flexible NO2 Sensors
Published 2025-01-01“…Comprehensive experimental investigations reveal mechanisms underlying this record sensitivity, that is, the use of N‐doped 2H MoS2 sensors not only significantly suppresses dark current but also effectively enhances electron transfer to NO2 molecules. Moreover, density function theory calculations underpin the experimental results, confirming that N2H4 molecules from the precursor solution not only promote phase transition but also enable N‐doping during post‐treatments, thus boosting sensing capability. …”
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179
Modulating the coordination environment of cobalt porphyrins for enhanced electrochemical nitrite reduction to ammonia
Published 2025-01-01“…In situ characterization and density functional theory calculations reveal that modulating the coordination environment alters the electron transfer mode of the cobalt active center and the charge redistribution caused by the break of the ligand field. …”
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180
A high-valence bismuth(V) nanoplatform triggers cancer cell death and anti-tumor immune responses with exogenous excitation-free endogenous H2O2- and O2-independent ROS generation
Published 2025-01-01“…Upon exposure to the tumor microenvironment, NaBiVO3-PEG undergoes continuous H+-accelerated hydrolysis with •OH and 1O2 generation through electron transfer-mediated BiV-to-BiIII conversion and lattice oxygen transformation. …”
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