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Non-metallic iodine single-atom catalysts with optimized electronic structures for efficient Fenton-like reactions
Published 2025-01-01“…This electron transfer is followed by a deprotonation process that generates the peroxymonosulfate radical (SO5 •−). …”
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42
Tracking the correlation between spintronic structure and oxygen evolution reaction mechanism of cobalt-ruthenium-based electrocatalyst
Published 2025-01-01“…Moreover, the ruthenium-cobalt-tin oxide possesses decoupled proton-electron transfer procedure during the oxygen evolution reaction process, demonstrating that the electron transfer procedure of O-O bond formation between *O intermediate and lattice oxygen in Co-O-Ru is the rate-determining step of the oxygen evolution reaction process. …”
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43
Sequential addition of cations increases photoluminescence quantum yield of metal nanoclusters near unity
Published 2025-01-01“…Moreover, introducing cation additives significantly reduces electron transfer time from 40, 27 to 12 ps in the pathway from staple motifs to the metal core. …”
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44
A Structural Model of Truncated Gaussia princeps Luciferase Elucidating the Crucial Catalytic Function of No.76 Arginine towards Coelenterazine Oxidation.
Published 2025-01-01“…Both intramolecular electron transfer and the convergence of S1/S0 potential energy surfaces occurred in the last elementary reaction, which was regarded as the reported Chemically-Initiated-Electron-Exchange-Luminescence (CIEEL) reaction. …”
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45
Electrodeposition of tin from EMI⋅BF4⋅Cl room temperature molten salts
Published 2003-01-01“…The deposition of tin proceeded through a quasi-reversible step with two electron transfer, and the deposited tin was sufficiently recovered during oxidation. …”
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46
Molecular Species Disturbing the Fluid–Solid Phase Transition of Nitrogen Adsorbed on Graphite: Importance of Aromaticity
Published 2000-09-01“…This implies that molecular properties such as cation acceptance and electron transfer are of no importance, whereas the aromaticity of co-existing species plays a crucial role in disturbing the phase behaviour of N 2 .…”
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47
Reversible multivalent carrier redox exceeding intercalation capacity boundary
Published 2025-01-01“…Abstract Compared with widely established monovalent-ion batteries, aqueous multivalent-ion batteries promise higher capacity release by achieving multiple electron-transfer events per ion intercalation in the host material. …”
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48
Liquid crystal template-assisted electrodeposition of nanoporous nickel microspheres: A sensitive electrochemical sensing platform for electrocatalytic oxidation and quantitative d...
Published 2025-02-01“…NNiMs were transformed into the corresponding oxides by applying consecutive potential cycles in an alkaline medium, and the electron transfer coefficient and apparent charge transfer rate constant of the redox species present on the modified electrode surface were calculated as 0.59 and 0.54 s−1, respectively. …”
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49
Dynamically Cyclic Fe2+/Fe3+ Active Sites as Electron and Proton-Feeding Centers Boosting CO2 Photoreduction Powered by Benzyl Alcohol Oxidation
Published 2025-01-01“…Solar-driven CO2 photoreduction holds promise for sustainable fuel and chemical productions, but the complex proton-coupled multi-electron transfer processes and sluggish oxidation half-reaction kinetics substantially hinder its efficiency. …”
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50
A DFT Analysis on Antioxidant and Antiradical Activities from Anthraquinones Isolated from the Cameroonian Flora
Published 2019-01-01“…The present work is devoted to the exploration antioxidant and antiradical activity of twenty anthraquinones isolated from the Cameroonian flora at B3LYP/6-311++G(d,p) level of theory using the B3LYP/6-31 + G(d,p) geometrical data as geometry optimization starting points. The single electron transfer mechanism has been adopted to examine both biological activities. …”
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51
Kinetic Study of the Oxidation of Catechols in the Presence of N-Methylaniline
Published 2013-01-01“…The reaction products are believed to be diphenylamine derivatives of catechols that undergo electron transfer at more negative potentials than the catechols. …”
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52
Potential of Zinc Oxide Nanostructures in Biosensor Application
Published 2025-01-01“…Their superior electron mobility enables effective electron transfer between the bioreceptor and transducer, enhancing sensitivity and reducing detection limits. …”
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53
Spectroscopic and Morphological Studies of Metal-Organic and Metal-Free Dyes onto Titania Films for Dye-Sensitized Solar Cells
Published 2013-01-01“…We have investigated the spectroscopic behavior of three different sensitizers adsorbed onto titania thin films in order to gain information both on the electron transfer process from dye to titania and on the anchorage of the chromophore onto the semiconductor. …”
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54
Unraveling the redox code to improve physiological research in human health and disease
Published 2024-11-01“…Abstract Redox reactions, involving electron transfer, are critical to human physiology. However, progress in understanding redox metabolism is hindered by flawed analytical methods. …”
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55
Electrogeneration of non-electroactive and non-conducting materials: a counterintuitive concept for the functionalization and nanostructuration of electrode surfaces
Published 2023-09-01“…., without direct electron transfer with the precursors). This account summarizes the major advances made by our group in this field, focusing primarily on electro-induced sol–gel bioencapsulation and electro-assisted self-assembly of oriented and functionalized mesoporous silica films.…”
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56
Phenolic Compounds Analysis of Root, Stalk, and Leaves of Nettle
Published 2012-01-01“…The antioxidant activity was measured by using DPPH (2,2-diphenyl-1-picrylhydrazyl) which is generally used for herbal samples and based on single electron transfer (SET).…”
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57
The Rieske Iron-Sulfur Protein: Import and Assembly into the Cytochrome 𝑏𝑐1 Complex of Yeast Mitochondria
Published 2011-01-01“…The Rieske iron-sulfur protein, one of the catalytic subunits of the cytochrome 𝑏𝑐1 complex, is involved in electron transfer at the level of the inner membrane of yeast mitochondria. …”
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58
Polarographic Determination and Antimicrobial Activity of Cu(II) Complex with 4-Chlorobenzylidene-4-aminoacetanilide
Published 2012-01-01“…The logarithm value of stability constant of Cu(II)-4-Chlorobenzylidene-4-aminoacetanilide (CAA) complex has been found to be 4.85.The redox properties of the complex was extensively investigated by electrochemical method using cyclic voltammetry (CV).The Cu(II) complexes exhibited quasi-reversible single electron transfer process.The Schiff base and its complex has been screened for their in-vitro antibacterial (Escherichiacoli, Staphylococcus aureus, Vibrio cholerae and Bacillus subtilis) and antifungal (Aspergillus niger and Penicillium liliacinum) activities by minimum inhibitory concentration (MIC) method.…”
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59
Electrochemical Behavior of Ni(II)-Salen at the Mercury Electrode
Published 2013-01-01“…The resulting voltammograms consist of a totally irreversible one-electron transfer attributable to the coupling of Ni(II) salen/Ni(I) salen via an EC mechanism. …”
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60
Management of Iron Overload in Resource Poor Nations: A Systematic Review of Phlebotomy and Natural Chelators
Published 2020-01-01“…Iron is an essential element and the most abundant trace metal in the body involved in oxygen transport and oxygen sensing, electron transfer, energy metabolism, and DNA synthesis. …”
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