Fouling and Chemical Cleaning Strategies for Submerged Ultrafiltration Membrane: Synchronized Bench-Scale, Full-Scale, and Engineering Tests
This study investigated membrane fouling issues associated with the operation of a submerged ultrafiltration membrane in a drinking water treatment plant (DWTP) and optimized the associated chemical cleaning strategies. By analyzing the surface components of the membrane foulant and the compositions...
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MDPI AG
2024-11-01
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| Series: | Membranes |
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| Online Access: | https://www.mdpi.com/2077-0375/14/12/251 |
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| author | Xiwang Zhu Chengyue Fan Yichen Fang Wenqing Yu Yawei Xie Hongyuan Liu |
| author_facet | Xiwang Zhu Chengyue Fan Yichen Fang Wenqing Yu Yawei Xie Hongyuan Liu |
| author_sort | Xiwang Zhu |
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| description | This study investigated membrane fouling issues associated with the operation of a submerged ultrafiltration membrane in a drinking water treatment plant (DWTP) and optimized the associated chemical cleaning strategies. By analyzing the surface components of the membrane foulant and the compositions of the membrane cleaning solution, the primary causes of membrane fouling were identified. Membrane fouling control strategies suitable for the DWTP were evaluated through chemical cleaning tests conducted for bench-scale, full-scale, and engineering cases. The results show that the membrane foulants were primarily composed of a mixture of inorganics and organics; the inorganics were mainly composed of Al and Si, while the organics were primarily humic acid (HA). Sodium citrate proved to be the most effective cleaning agent for inorganic fouling, which was mainly composed of Al, whereas sodium hypochlorite (NaClO) combined with sodium hydroxide (NaOH) showed the best removal efficiency for organic fouling, which predominantly consisted of HA and Si. However, sodium hypochlorite (NaClO) combined with sodium hydroxide (NaOH) showed the best removal efficiency for organic fouling and Si; organic fouling predominantly consisted of HA. Based on the bench-scale test results, flux recovery was verified in the full-scale system. Under a constant pressure of 30 kPa, the combined acid–alkali cleaning achieved the best flux recovery, restoring the flux from 22.8 L/(m<sup>2</sup>·h) to 66.75 L/(m<sup>2</sup>·h). In the engineering tests, combined acid–alkali cleaning yielded results consistent with those of the full-scale tests. In the practical engineering cleaning process, adopting a cleaning strategy of alkaline (NaClO + NaOH) cleaning followed by acidic (sodium citrate) cleaning can effectively solve the membrane fouling problem. |
| format | Article |
| id | doaj-art-f42c2179bfe34e658eb4b54e7b424d6a |
| institution | Kabale University |
| issn | 2077-0375 |
| language | English |
| publishDate | 2024-11-01 |
| publisher | MDPI AG |
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| series | Membranes |
| spelling | doaj-art-f42c2179bfe34e658eb4b54e7b424d6a2024-12-27T14:39:19ZengMDPI AGMembranes2077-03752024-11-01141225110.3390/membranes14120251Fouling and Chemical Cleaning Strategies for Submerged Ultrafiltration Membrane: Synchronized Bench-Scale, Full-Scale, and Engineering TestsXiwang Zhu0Chengyue Fan1Yichen Fang2Wenqing Yu3Yawei Xie4Hongyuan Liu5College of Civil Engineering, Zhejiang University of Technology, Hangzhou 310023, ChinaCollege of Civil Engineering, Zhejiang University of Technology, Hangzhou 310023, ChinaCollege of Civil Engineering, Zhejiang University of Technology, Hangzhou 310023, ChinaZhejiang Supcon Information Co., Ltd., Hangzhou 310056, ChinaCollege of Civil Engineering, Zhejiang University of Technology, Hangzhou 310023, ChinaCollege of Civil Engineering, Zhejiang University of Technology, Hangzhou 310023, ChinaThis study investigated membrane fouling issues associated with the operation of a submerged ultrafiltration membrane in a drinking water treatment plant (DWTP) and optimized the associated chemical cleaning strategies. By analyzing the surface components of the membrane foulant and the compositions of the membrane cleaning solution, the primary causes of membrane fouling were identified. Membrane fouling control strategies suitable for the DWTP were evaluated through chemical cleaning tests conducted for bench-scale, full-scale, and engineering cases. The results show that the membrane foulants were primarily composed of a mixture of inorganics and organics; the inorganics were mainly composed of Al and Si, while the organics were primarily humic acid (HA). Sodium citrate proved to be the most effective cleaning agent for inorganic fouling, which was mainly composed of Al, whereas sodium hypochlorite (NaClO) combined with sodium hydroxide (NaOH) showed the best removal efficiency for organic fouling, which predominantly consisted of HA and Si. However, sodium hypochlorite (NaClO) combined with sodium hydroxide (NaOH) showed the best removal efficiency for organic fouling and Si; organic fouling predominantly consisted of HA. Based on the bench-scale test results, flux recovery was verified in the full-scale system. Under a constant pressure of 30 kPa, the combined acid–alkali cleaning achieved the best flux recovery, restoring the flux from 22.8 L/(m<sup>2</sup>·h) to 66.75 L/(m<sup>2</sup>·h). In the engineering tests, combined acid–alkali cleaning yielded results consistent with those of the full-scale tests. In the practical engineering cleaning process, adopting a cleaning strategy of alkaline (NaClO + NaOH) cleaning followed by acidic (sodium citrate) cleaning can effectively solve the membrane fouling problem.https://www.mdpi.com/2077-0375/14/12/251submerged ultrafiltration membraneflux recoverymembrane foulingchemical cleaningfouling control strategies |
| spellingShingle | Xiwang Zhu Chengyue Fan Yichen Fang Wenqing Yu Yawei Xie Hongyuan Liu Fouling and Chemical Cleaning Strategies for Submerged Ultrafiltration Membrane: Synchronized Bench-Scale, Full-Scale, and Engineering Tests Membranes submerged ultrafiltration membrane flux recovery membrane fouling chemical cleaning fouling control strategies |
| title | Fouling and Chemical Cleaning Strategies for Submerged Ultrafiltration Membrane: Synchronized Bench-Scale, Full-Scale, and Engineering Tests |
| title_full | Fouling and Chemical Cleaning Strategies for Submerged Ultrafiltration Membrane: Synchronized Bench-Scale, Full-Scale, and Engineering Tests |
| title_fullStr | Fouling and Chemical Cleaning Strategies for Submerged Ultrafiltration Membrane: Synchronized Bench-Scale, Full-Scale, and Engineering Tests |
| title_full_unstemmed | Fouling and Chemical Cleaning Strategies for Submerged Ultrafiltration Membrane: Synchronized Bench-Scale, Full-Scale, and Engineering Tests |
| title_short | Fouling and Chemical Cleaning Strategies for Submerged Ultrafiltration Membrane: Synchronized Bench-Scale, Full-Scale, and Engineering Tests |
| title_sort | fouling and chemical cleaning strategies for submerged ultrafiltration membrane synchronized bench scale full scale and engineering tests |
| topic | submerged ultrafiltration membrane flux recovery membrane fouling chemical cleaning fouling control strategies |
| url | https://www.mdpi.com/2077-0375/14/12/251 |
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