Coordination of <i>O</i>-Propyl-<i>N</i>-phenylthiocarbamate to HgI<sub>2</sub> and the Crystallographic Characterization of an Anilinium Chloride Thiocarbamate Adduct
In order to investigate the coordination chemistry of <i>O</i>-alkyl <i>N</i>-aryl thiocarbamate ligands, HgI<sub>2</sub> was reacted with one equivalent of PrOC(=S)N(H)Ph <b>L</b> in toluene solution to afford the 1D polymeric title compound [{IHg(μ-I...
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2024-11-01
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| author | Wafa Arar Nuri Ekici Michael Knorr Isabelle Jourdain Carsten Strohmann Jan-Lukas Kirchhoff |
| author_facet | Wafa Arar Nuri Ekici Michael Knorr Isabelle Jourdain Carsten Strohmann Jan-Lukas Kirchhoff |
| author_sort | Wafa Arar |
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| description | In order to investigate the coordination chemistry of <i>O</i>-alkyl <i>N</i>-aryl thiocarbamate ligands, HgI<sub>2</sub> was reacted with one equivalent of PrOC(=S)N(H)Ph <b>L</b> in toluene solution to afford the 1D polymeric title compound [{IHg(μ-I)}{κ<sup>1</sup>-PrOC(=S)N(H)Ph}]<i><sub>n</sub></i> <b>CP1</b>. The formation of this iodide-bridged coordination polymer was ascertained by a single-crystal X-ray diffraction study performed at 100 K, as well as the formation of an adduct between anilinium chloride and <b>L</b> forming a supramolecular ribbon of composition [<b>L(PhNH<sub>3</sub>)(Cl)</b>]. The occurrence of anilinium chloride is due to the partial hydrolysis of <b>L</b> in the presence of HCl. |
| format | Article |
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| institution | Kabale University |
| issn | 1422-8599 |
| language | English |
| publishDate | 2024-11-01 |
| publisher | MDPI AG |
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| spelling | doaj-art-f385c986d33f42e99bf4dddbb9819b0a2024-12-27T14:42:16ZengMDPI AGMolbank1422-85992024-11-0120244M192310.3390/M1923Coordination of <i>O</i>-Propyl-<i>N</i>-phenylthiocarbamate to HgI<sub>2</sub> and the Crystallographic Characterization of an Anilinium Chloride Thiocarbamate AdductWafa Arar0Nuri Ekici1Michael Knorr2Isabelle Jourdain3Carsten Strohmann4Jan-Lukas Kirchhoff5Selective Organic-Heterocyclic Synthesis-Biological Activity Evaluation (LR17ESO01), Université de Tunis-El Manar, Tunis 2092, TunisiaInstitut UTINAM UMR 6213 CNRS, Université de Franche-Comté, 16, Route de Gray, 25030 Besançon, FranceInstitut UTINAM UMR 6213 CNRS, Université de Franche-Comté, 16, Route de Gray, 25030 Besançon, FranceInstitut UTINAM UMR 6213 CNRS, Université de Franche-Comté, 16, Route de Gray, 25030 Besançon, FranceAnorganische Chemie, Technische Universität Dortmund, Otto-Hahn Straße 6, 44227 Dortmund, GermanyAnorganische Chemie, Technische Universität Dortmund, Otto-Hahn Straße 6, 44227 Dortmund, GermanyIn order to investigate the coordination chemistry of <i>O</i>-alkyl <i>N</i>-aryl thiocarbamate ligands, HgI<sub>2</sub> was reacted with one equivalent of PrOC(=S)N(H)Ph <b>L</b> in toluene solution to afford the 1D polymeric title compound [{IHg(μ-I)}{κ<sup>1</sup>-PrOC(=S)N(H)Ph}]<i><sub>n</sub></i> <b>CP1</b>. The formation of this iodide-bridged coordination polymer was ascertained by a single-crystal X-ray diffraction study performed at 100 K, as well as the formation of an adduct between anilinium chloride and <b>L</b> forming a supramolecular ribbon of composition [<b>L(PhNH<sub>3</sub>)(Cl)</b>]. The occurrence of anilinium chloride is due to the partial hydrolysis of <b>L</b> in the presence of HCl.https://www.mdpi.com/1422-8599/2024/4/M1923mercury iodidethiocarbamatethionecrystal structureanilinium salt |
| spellingShingle | Wafa Arar Nuri Ekici Michael Knorr Isabelle Jourdain Carsten Strohmann Jan-Lukas Kirchhoff Coordination of <i>O</i>-Propyl-<i>N</i>-phenylthiocarbamate to HgI<sub>2</sub> and the Crystallographic Characterization of an Anilinium Chloride Thiocarbamate Adduct Molbank mercury iodide thiocarbamate thione crystal structure anilinium salt |
| title | Coordination of <i>O</i>-Propyl-<i>N</i>-phenylthiocarbamate to HgI<sub>2</sub> and the Crystallographic Characterization of an Anilinium Chloride Thiocarbamate Adduct |
| title_full | Coordination of <i>O</i>-Propyl-<i>N</i>-phenylthiocarbamate to HgI<sub>2</sub> and the Crystallographic Characterization of an Anilinium Chloride Thiocarbamate Adduct |
| title_fullStr | Coordination of <i>O</i>-Propyl-<i>N</i>-phenylthiocarbamate to HgI<sub>2</sub> and the Crystallographic Characterization of an Anilinium Chloride Thiocarbamate Adduct |
| title_full_unstemmed | Coordination of <i>O</i>-Propyl-<i>N</i>-phenylthiocarbamate to HgI<sub>2</sub> and the Crystallographic Characterization of an Anilinium Chloride Thiocarbamate Adduct |
| title_short | Coordination of <i>O</i>-Propyl-<i>N</i>-phenylthiocarbamate to HgI<sub>2</sub> and the Crystallographic Characterization of an Anilinium Chloride Thiocarbamate Adduct |
| title_sort | coordination of i o i propyl i n i phenylthiocarbamate to hgi sub 2 sub and the crystallographic characterization of an anilinium chloride thiocarbamate adduct |
| topic | mercury iodide thiocarbamate thione crystal structure anilinium salt |
| url | https://www.mdpi.com/1422-8599/2024/4/M1923 |
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