Semiconducting Characteristic of Antiferromagnetic Al4X3Mn (X = P, As and Sb) Compounds with Ab Initio Simulation Methods

This research reports the electronic characteristics of ternary aluminium-based Al4X3Mn (X=P, As and Sb) compounds for the most stable magnetic order which is A-type antiferromagnetic. The related systems are comforming 215 space number with P-43m space group which is simple cubic crystal structure....

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Main Authors: Aytaç Erkişi, Buğra Yıldız
Format: Article
Language:English
Published: Sakarya University 2024-04-01
Series:Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi
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Online Access:https://dergipark.org.tr/tr/download/article-file/3316576
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author Aytaç Erkişi
Buğra Yıldız
author_facet Aytaç Erkişi
Buğra Yıldız
author_sort Aytaç Erkişi
collection DOAJ
description This research reports the electronic characteristics of ternary aluminium-based Al4X3Mn (X=P, As and Sb) compounds for the most stable magnetic order which is A-type antiferromagnetic. The related systems are comforming 215 space number with P-43m space group which is simple cubic crystal structure. The computations in this research have been done within the framework of Density Functional Theory. The calculations utilized Perdew-Burke-Ernzerhof type correlation functionals within the meta-generalized gradient approximation. For considered four different type magnetic orders, the visualized volume-energy plots and the calculated formation energy values imply that the magnetic nature of these compositions is A-type antiferromagnetic. Besides, the investigated electronic natures in the detected stable magnetic phase of these systems are semiconductor since the band gaps were observed in their electronic band structures and density of states (Eg = 0.36 eV for Al4P3Mn, Eg = 0.33 eV for Al4As3Mn, and Eg = 0.18 eV for Al4Sb3Mn).
format Article
id doaj-art-f2bc6bdda7a349b19ffc0f256d7c5e97
institution Kabale University
issn 2147-835X
language English
publishDate 2024-04-01
publisher Sakarya University
record_format Article
series Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi
spelling doaj-art-f2bc6bdda7a349b19ffc0f256d7c5e972024-12-23T08:17:25ZengSakarya UniversitySakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi2147-835X2024-04-0128232633210.16984/saufenbilder.133968528Semiconducting Characteristic of Antiferromagnetic Al4X3Mn (X = P, As and Sb) Compounds with Ab Initio Simulation MethodsAytaç Erkişi0https://orcid.org/0000-0001-7995-7590Buğra Yıldız1https://orcid.org/0000-0002-0080-7096PAMUKKALE UNIVERSITYHACETTEPE UNIVERSITYThis research reports the electronic characteristics of ternary aluminium-based Al4X3Mn (X=P, As and Sb) compounds for the most stable magnetic order which is A-type antiferromagnetic. The related systems are comforming 215 space number with P-43m space group which is simple cubic crystal structure. The computations in this research have been done within the framework of Density Functional Theory. The calculations utilized Perdew-Burke-Ernzerhof type correlation functionals within the meta-generalized gradient approximation. For considered four different type magnetic orders, the visualized volume-energy plots and the calculated formation energy values imply that the magnetic nature of these compositions is A-type antiferromagnetic. Besides, the investigated electronic natures in the detected stable magnetic phase of these systems are semiconductor since the band gaps were observed in their electronic band structures and density of states (Eg = 0.36 eV for Al4P3Mn, Eg = 0.33 eV for Al4As3Mn, and Eg = 0.18 eV for Al4Sb3Mn).https://dergipark.org.tr/tr/download/article-file/3316576density functional theoryab-initio simulation methodssemiconductor
spellingShingle Aytaç Erkişi
Buğra Yıldız
Semiconducting Characteristic of Antiferromagnetic Al4X3Mn (X = P, As and Sb) Compounds with Ab Initio Simulation Methods
Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi
density functional theory
ab-initio simulation methods
semiconductor
title Semiconducting Characteristic of Antiferromagnetic Al4X3Mn (X = P, As and Sb) Compounds with Ab Initio Simulation Methods
title_full Semiconducting Characteristic of Antiferromagnetic Al4X3Mn (X = P, As and Sb) Compounds with Ab Initio Simulation Methods
title_fullStr Semiconducting Characteristic of Antiferromagnetic Al4X3Mn (X = P, As and Sb) Compounds with Ab Initio Simulation Methods
title_full_unstemmed Semiconducting Characteristic of Antiferromagnetic Al4X3Mn (X = P, As and Sb) Compounds with Ab Initio Simulation Methods
title_short Semiconducting Characteristic of Antiferromagnetic Al4X3Mn (X = P, As and Sb) Compounds with Ab Initio Simulation Methods
title_sort semiconducting characteristic of antiferromagnetic al4x3mn x p as and sb compounds with ab initio simulation methods
topic density functional theory
ab-initio simulation methods
semiconductor
url https://dergipark.org.tr/tr/download/article-file/3316576
work_keys_str_mv AT aytacerkisi semiconductingcharacteristicofantiferromagnetical4x3mnxpasandsbcompoundswithabinitiosimulationmethods
AT bugrayıldız semiconductingcharacteristicofantiferromagnetical4x3mnxpasandsbcompoundswithabinitiosimulationmethods