Crystal structures and supramolecular interactions of prism[6]arene-based host–guest systems with dihalohexanes
The crystal structures of the supramolecular systems formed by perethoxy prism[6]arene (PS6) with 1,6-dichlorohexane (HexCl2), C90H96O12·2C6H12Cl2, and 1,6-diiodohexane (HexI2), C90H96O12·2C6H12I2, are reported. PS6 encapsulates these linear dihaloalkanes, creating 1:1 host–guest systems (PS6·HexCl2...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2025-06-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | https://journals.iucr.org/paper?S2056989025003767 |
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| Summary: | The crystal structures of the supramolecular systems formed by perethoxy prism[6]arene (PS6) with 1,6-dichlorohexane (HexCl2), C90H96O12·2C6H12Cl2, and 1,6-diiodohexane (HexI2), C90H96O12·2C6H12I2, are reported. PS6 encapsulates these linear dihaloalkanes, creating 1:1 host–guest systems (PS6·HexCl2 and PS6·HexI2). The structural details and host–guest intermolecular interactions within the crystal networks are presented and discussed. In both crystal structures, the prism[6]arene macrocycle adopts a distorted cuboid shape, with the guest positioned perpendicular to its main axis. |
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| ISSN: | 2056-9890 |