Adsorption Concentration of Platinum Metals by Clinoptilolite

Ruthenium(IV) and palladium(II) adsorption from aqueous solutions on to Transcarpathian clinoptilolite has been studied under dynamic conditions. The optimum conditions for ruthenium(IV) adsorption from aqueous solutions have been established as follows: pH = 3.5–4.5 or 9.0–11.0; radius of adsorbent...

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Main Authors: T. Ya. Vrublevs'ka, L.V. Vrons'ka, O.Ya. Korkuna, N.M. Matviychouk
Format: Article
Language:English
Published: SAGE Publishing 1999-01-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/026361749901700104
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author T. Ya. Vrublevs'ka
L.V. Vrons'ka
O.Ya. Korkuna
N.M. Matviychouk
author_facet T. Ya. Vrublevs'ka
L.V. Vrons'ka
O.Ya. Korkuna
N.M. Matviychouk
author_sort T. Ya. Vrublevs'ka
collection DOAJ
description Ruthenium(IV) and palladium(II) adsorption from aqueous solutions on to Transcarpathian clinoptilolite has been studied under dynamic conditions. The optimum conditions for ruthenium(IV) adsorption from aqueous solutions have been established as follows: pH = 3.5–4.5 or 9.0–11.0; radius of adsorbent particles, 0.200–0.355 mm; and velocity of solution passing through the adsorbent, 3 mm/min. For palladium adsorption from aqueous nitric acid (pH = 4.0) and ammonia (pH = 11.5) solutions, the optimum radius of the adsorbent particles was in the 0.355–0.500 mm range. Desorption of Ru IV and Pd II was performed using 6 M hydrochloric acid. The degree of ruthenium(IV) extraction under optimum conditions was 95% and for palladium(II) extraction from nitric acid and ammonia solutions the corresponding values were 81.5% and 96.8%, respectively.
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institution Kabale University
issn 0263-6174
2048-4038
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publishDate 1999-01-01
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record_format Article
series Adsorption Science & Technology
spelling doaj-art-ec492214cbcf4ae1b6dca001e22daba52025-01-03T00:10:30ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40381999-01-011710.1177/026361749901700104Adsorption Concentration of Platinum Metals by ClinoptiloliteT. Ya. Vrublevs'kaL.V. Vrons'kaO.Ya. KorkunaN.M. MatviychoukRuthenium(IV) and palladium(II) adsorption from aqueous solutions on to Transcarpathian clinoptilolite has been studied under dynamic conditions. The optimum conditions for ruthenium(IV) adsorption from aqueous solutions have been established as follows: pH = 3.5–4.5 or 9.0–11.0; radius of adsorbent particles, 0.200–0.355 mm; and velocity of solution passing through the adsorbent, 3 mm/min. For palladium adsorption from aqueous nitric acid (pH = 4.0) and ammonia (pH = 11.5) solutions, the optimum radius of the adsorbent particles was in the 0.355–0.500 mm range. Desorption of Ru IV and Pd II was performed using 6 M hydrochloric acid. The degree of ruthenium(IV) extraction under optimum conditions was 95% and for palladium(II) extraction from nitric acid and ammonia solutions the corresponding values were 81.5% and 96.8%, respectively.https://doi.org/10.1177/026361749901700104
spellingShingle T. Ya. Vrublevs'ka
L.V. Vrons'ka
O.Ya. Korkuna
N.M. Matviychouk
Adsorption Concentration of Platinum Metals by Clinoptilolite
Adsorption Science & Technology
title Adsorption Concentration of Platinum Metals by Clinoptilolite
title_full Adsorption Concentration of Platinum Metals by Clinoptilolite
title_fullStr Adsorption Concentration of Platinum Metals by Clinoptilolite
title_full_unstemmed Adsorption Concentration of Platinum Metals by Clinoptilolite
title_short Adsorption Concentration of Platinum Metals by Clinoptilolite
title_sort adsorption concentration of platinum metals by clinoptilolite
url https://doi.org/10.1177/026361749901700104
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