Complexes of polyvinylpyrrolidone and polyethylene glycol with palladium(II) ions: characterization and catalytic activity
In this work, we obtained complexes by mixing aqueous solution of palladium(II) chloride with polyvinylpyrrolidone and polyethylene glycol. The composition of the complex compounds was determined by potentiometric and conductometric titration. IR spectroscopy and scanning electron microscopy (SEM) c...
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| Format: | Article |
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Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
2023-07-01
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| Series: | Chimica Techno Acta |
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| Online Access: | https://chimicatechnoacta.ru/article/view/6889 |
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| author | Dina N. Akbayeva Indira A. Smagulova Azhar Timurkyzy Botagoz S. Bakirova |
| author_facet | Dina N. Akbayeva Indira A. Smagulova Azhar Timurkyzy Botagoz S. Bakirova |
| author_sort | Dina N. Akbayeva |
| collection | DOAJ |
| description | In this work, we obtained complexes by mixing aqueous solution of palladium(II) chloride with polyvinylpyrrolidone and polyethylene glycol. The composition of the complex compounds was determined by potentiometric and conductometric titration. IR spectroscopy and scanning electron microscopy (SEM) confirmed the coordination of polymeric ligand to palladium and allowed evaluating the morphology and features of the complex surface. The catalytic activity of the synthesized compounds in the oxidation of octene-1 by inorganic oxidizers (NaBrO3, K2S2O8) in aqueous-organic media in dimethyl sulfoxide (DMSO) under mild conditions was calculated. The reaction product was octanone-2, obtained in good yield (62–98%). Quantitative analysis of octanone-2 was made by the gas-chromatographic method. Mass spectrometry confirms the formation of octanone-2. The complexes are able to participate in five consecutive catalytic cycles without significant loss of catalytic efficiency. Oxidation of octene-1 proceeds by the oxidation-reduction mechanism and consists of two key stages. |
| format | Article |
| id | doaj-art-ebe7328af18a4d15abcea8da4c7c126f |
| institution | Kabale University |
| issn | 2411-1414 |
| language | English |
| publishDate | 2023-07-01 |
| publisher | Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina |
| record_format | Article |
| series | Chimica Techno Acta |
| spelling | doaj-art-ebe7328af18a4d15abcea8da4c7c126f2024-12-25T09:36:55ZengUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. ElʹcinaChimica Techno Acta2411-14142023-07-0110310.15826/chimtech.2023.10.3.014954Complexes of polyvinylpyrrolidone and polyethylene glycol with palladium(II) ions: characterization and catalytic activityDina N. Akbayeva0Indira A. Smagulova1Azhar Timurkyzy2Botagoz S. Bakirova3Al-Farabi Kazakh National UniversityAl-Farabi Kazakh National UniversityAl-Farabi Kazakh National UniversityAl-Farabi Kazakh National UniversityIn this work, we obtained complexes by mixing aqueous solution of palladium(II) chloride with polyvinylpyrrolidone and polyethylene glycol. The composition of the complex compounds was determined by potentiometric and conductometric titration. IR spectroscopy and scanning electron microscopy (SEM) confirmed the coordination of polymeric ligand to palladium and allowed evaluating the morphology and features of the complex surface. The catalytic activity of the synthesized compounds in the oxidation of octene-1 by inorganic oxidizers (NaBrO3, K2S2O8) in aqueous-organic media in dimethyl sulfoxide (DMSO) under mild conditions was calculated. The reaction product was octanone-2, obtained in good yield (62–98%). Quantitative analysis of octanone-2 was made by the gas-chromatographic method. Mass spectrometry confirms the formation of octanone-2. The complexes are able to participate in five consecutive catalytic cycles without significant loss of catalytic efficiency. Oxidation of octene-1 proceeds by the oxidation-reduction mechanism and consists of two key stages.https://chimicatechnoacta.ru/article/view/6889palladium(ii) ionspolyvinylpyrrolidonepolyethylene glycolcatalysisoxidationoctene-1 |
| spellingShingle | Dina N. Akbayeva Indira A. Smagulova Azhar Timurkyzy Botagoz S. Bakirova Complexes of polyvinylpyrrolidone and polyethylene glycol with palladium(II) ions: characterization and catalytic activity Chimica Techno Acta palladium(ii) ions polyvinylpyrrolidone polyethylene glycol catalysis oxidation octene-1 |
| title | Complexes of polyvinylpyrrolidone and polyethylene glycol with palladium(II) ions: characterization and catalytic activity |
| title_full | Complexes of polyvinylpyrrolidone and polyethylene glycol with palladium(II) ions: characterization and catalytic activity |
| title_fullStr | Complexes of polyvinylpyrrolidone and polyethylene glycol with palladium(II) ions: characterization and catalytic activity |
| title_full_unstemmed | Complexes of polyvinylpyrrolidone and polyethylene glycol with palladium(II) ions: characterization and catalytic activity |
| title_short | Complexes of polyvinylpyrrolidone and polyethylene glycol with palladium(II) ions: characterization and catalytic activity |
| title_sort | complexes of polyvinylpyrrolidone and polyethylene glycol with palladium ii ions characterization and catalytic activity |
| topic | palladium(ii) ions polyvinylpyrrolidone polyethylene glycol catalysis oxidation octene-1 |
| url | https://chimicatechnoacta.ru/article/view/6889 |
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