Attosecond spectroscopy of molecular charge transfer uncovers a 1.5-fs delay in population transfer

Abstract The transfer of population between two intersecting quantum states is the most fundamental event in many dynamical processes in physics, chemistry, biology, and material science. Any two-state description of such processes requires population leaving one state to instantaneously appear in t...

Full description

Saved in:
Bibliographic Details
Main Authors: Danylo T. Matselyukh, Florian Rott, Thomas Schnappinger, Pengju Zhang, Zheng Li, Jeremy O. Richardson, Regina de Vivie-Riedle, Hans Jakob Wörner
Format: Article
Language:English
Published: Nature Portfolio 2025-08-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-62162-6
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Abstract The transfer of population between two intersecting quantum states is the most fundamental event in many dynamical processes in physics, chemistry, biology, and material science. Any two-state description of such processes requires population leaving one state to instantaneously appear in the other. We show that coupling to additional states, present in all real-world systems, can cause a measurable delay in population transfer. Using attosecond spectroscopy supported by quantum-chemical calculations, we measure a delay of 1.46 ± 0.41 fs at a charge-transfer crossing in CF3I+, where an electron hole moves from the fluorine atoms to iodine. Our measurements also resolve the other fundamental quantum-dynamical processes involved in the charge-transfer reaction: a vibrational rearrangement time of 9.38 ± 0.21 fs (during which the vibrational wave packet travels to the state crossing) and a population-transfer time of 2.3–2.4 fs. Our work shows that delays in population transfer readily appear in otherwise-adiabatic reactions and predicts them to be on the order of a single-femtosecond for molecular valence-state crossings. These results have implications for many research areas, such as atomic and molecular physics, charge transfer, or light harvesting.
ISSN:2041-1723